Julen Lopetegui's side were awarded a penalty early in the game after a VAR review determined forward Nolito had been fouled by Valladolid's Javi Moyano as he shaped to shoot, even though his team mates had barely appealed for a foul.
The following factbox details five times a Video Assistant Referee (VAR) made an impact at the World Cup.
Al-Ahli secured a 3-1 win over 10-man Al-Hilal to win the battle of the Saudi Pro League sides in Jeddah on Tuesday, booking a place in Saturday's final of the Asian Champions League Elite to keep their dream of a first continental title alive.
Wolverhampton Wanderers had a goal controversially ruled out by VAR as they were held to a 0-0 draw at home to Leicester City, who finished with 10 men, in the Premier League on Friday.
Chelsea beat London rivals Tottenham Hotspur 1-0 on Thursday thanks to a goal by Argentina's Enzo Fernandez
A round-up of Wednesday's Champions League quarter-final second leg between Real Madrid and Arsenal, Inter Milan and Bayern Munich.
Bournemouth's Antoine Semenyo scored inside the first minute as they ended a run of eight games without a victory thanks to a 1-0 Premier League home win over Fulham on Monday, a result that reignites their hopes of European football next season.
Millwall goalkeeper Liam Roberts has had his suspension for a high-footed challenge on Crystal Palace forward Jean-Philippe Mateta extended to six matches, the FA said on Friday.
Images from the Serie A and La Liga matches played on Saturday.
Nuno Espirito Santo's side took the lead after five minutes when a corner fell to Elliot Anderson on the edge of the area and his powerful deflected drive found the net.
Liverpool continued their march towards the Premier League title with a 1-0 victory over Everton in a scrappy Merseyside derby as Diogo Jota slotted home the winner in the second half on Wednesday.
IMAGES from the English Premier League match played between Arsenal and Chelsea at Emirates Stadium in London on Sunday.
Arsenal snapped a season-long jinx against Newcastle United with a nervy 1-0 win in their last Premier League home game on Sunday.
Images from Friday's Premier League matches between Chelsea and Manchester United, Aston Villa and Tottenham Hotspur.
European soccer's governing body opted against using VAR this season, despite the technology being employed by major European leagues in Spain, Italy and Germany, and the World Cup in Russia this year.
Manchester City's Matheus Nunes scored deep in injury time to salvage a crucial 2-1 Premier League victory over Aston Villa on Tuesday in their breathless chase for a Champions League berth next season.
Atletico had no shots on target until the referee awarded them the penalty for a handball by Getafe defender Omar Alderete which Sorloth netted with a low strike to the goalkeeper's left.
Newcastle United registered a 2-0 home win over Chelsea on Sunday that moves the Magpies a step closer to Champions League football next season.
Manchester City forward Gabriel Jesus became the first player to have a goal disallowed by the Video Assistant Referee (VAR) in the English Premier League.
Liverpool roared back from a goal behind to thrash Tottenham Hotspur 5-1 and wrap up the English Premier League title in style.
A Jules Kounde goal in the dying minutes of extra-time handed Barcelona a dramatic 3-2 win over fierce rivals Real Madrid in an enthralling Copa del Rey final on Saturday.
'People sitting in the stands need to know what the rules are. Who is refereeing the game? We need to know. People deserve to know what are the rules of the game and the game belongs to the people.'
However, referee Bruno Correia gave only a yellow card and VAR did not consider it worthy of a review.
Images from Saturday's action in the Premier League.
Tottenham Hotspur gained a slender advantage in their League Cup semi-final against London rivals Chelsea as Harry Kane's penalty earned them a gritty 1-0 first-leg win.
Villarreal fought back to shock Barcelona 3-2 on Sunday, handing the LaLiga champions their first league defeat since late December.
News of all that's transpired on and off the football field
Llorente's second-half treble, a double from Son Heung-min and a late effort from Kyle Walker-Peters in driving snow at a freezing Wembley Stadium settled an game where tensions had threatened to bubble over before the break.
'I haven't heard any serious proposals regarding the protection of the referees'
A debatable penalty awarded with the use of FIFA's new video replay system proved a turning point in the World Cup final on Sunday and raised more questions over whether the new technology is being used in the way it was originally intended.
Lionel Messi kept his nerve from the penalty spot to give Barcelona a 1-0 win over Real Sociedad in La Liga on Saturday and return his side to the top of the table.
Striker Robert Lewandowski scored a first-half penalty to give Barcelona a hard-fought 1-0 home win over Rayo Vallecano.
Championship side Derby County hit back from two goals down to beat Premier League Southampton on penalties in an FA Cup third-round replay marred by another VAR controversy on Wednesday.
Iraq want their World Cup qualifier against Palestine next month moved from the Jordanian capital of Amman, having also knocked back a Palestinian proposal to stage the match just outside Jerusalem.
Images from the Europa League semi-finals first Leg between Athletic Bilbao and Manchester United, Tottenham Hotspur and Bodo/Glimt.
Video Assistant Referees (VARs) will be making their debut at the World Cup in Russia this month but the technology will not be perfect, FIFA's director of refereeing, Massimo Busacca, warned on Tuesday.
A summary of Saturday's action in LaLiga, Serie A, Bundesliga and Ligue 1.
Images from Saturday's La Liga action.
IMAGES from the Premier League matches played on Sunday.
With a game in hand, Hansi Flick's Barca are top on 66 points, three ahead Real in second