Paris St Germain overcame a two-goal deficit and a horror start to beat 10-man Monaco 3-2 in the first leg of their Champions League knockout round playoff tie.
Mbappe fires Real Madrid to the summit, Bayern lose at home and Dortmund stay in the title hunt.
Championship side Oxford United beat League Two's MK Dons on penalties after their match ended 1-1, while a couple of League One teams moved on, with Wigan Athletic beating Championship side Preston North End 1-0, and Port Vale defeating League Two's Fleetwood Town 1-0.
A round-up of Tuesday's action in the UEFA Champions League.
IMAGES from matches played across European leagues on Saturday
Real Madrid hit their stride at the Club World Cup on Tuesday, edging Juventus 1-0 to reach the quarter-finals thanks to a second-half strike from academy graduate Gonzalo Garcia.
Manchester City's Erling Haaland extended his remarkable scoring streak to 12 straight matches as his side recorded a comfortable 2-0 victory at Villarreal in the Champions League on Tuesday.
Images from the Club World Cup match between Borussia Dortmund and Mamelodi Sundowns at TQL Stadium, Cincinnati, Ohio, on Saturday.
Nine players from treble-winning Paris St Germain have been nominated for the men's Ballon d'Or this year along with the club's coach Luis Enrique as France Football announced the list of nominees on Thursday.
A round-up of Tuesday's Champions League quarter-finals second leg between Barcelona and Dortmund, Aston Villa and Paris St Germain.
Images from the Club World Cup quarter-finals between Paris St Germain-Bayern Munich and Real Madrid-Dortmund.
Paris St Germain seized control of their Champions League playoff with a commanding 3-0 first-leg win at Brest on Tuesday, driven by a brace from forward Ousmane Dembele.
Manchester City came from behind to beat Club Brugge 3-1 and secure their place in the Champions League playoffs
A summary of Wednesday's action in the UEFA Champions League Knock-out phase play-offs.
Paris St. Germain's unbeaten start to their Ligue 1 season continued on Friday with a comfortable 3-1 win over Rennes at the Parc des Princes that saw Bradley Barcola score twice to keep them top of the standings.
A summary of Saturday's action in LaLiga, Bundesliga and Serie A.
A summary of Saturday's action in the LaLiga, Serie A and Bundesliga.
A summary of Wednesday's Champions League Round of 16, Second Leg, matches.
Manchester City have one just victory from their last 10 games across all competitions.
Barcelona's Raphinha scored deep into stoppage time to hand his side a dramatic 5-4 comeback win at Benfica and a place in the Champions League last 16.
Barcelona striker Robert Lewandowski scored twice to set his side on course for a 5-0 Champions League thrashing of Swiss side Young Boys on Tuesday as the Catalan giants bounced back from a 2-1 loss at AS Monaco in their opener.
Liverpool's Luis Diaz scored a hat-trick as they maintained their perfect Champions League campaign with a barnstorming second-half display in a 4-0 victory over Xabi Alonso's Bayer Leverkusen at Anfield on Tuesday.
Bayern Munich earned a nervous 1-0 win at St Pauli thanks to a sensational 28-metre drive from Jamal Musiala to stay unbeaten.
Inter Milan escaped Etihad Stadium with a surprise 0-0 draw against Manchester City in the Champions League on Wednesday.
IMAGES from the UEFA Champions League matches played on Wednesday
Bayern Munich conceded a stoppage-time equaliser through VfB Stuttgart striker Serhou Guirassy from the penalty spot for a 2-2 on Saturday, the champions' third consecutive Bundesliga draw.
IMAGES from the football matches played across Europe on Sunday.
Paris St Germain's second-string side were held to a 4-4 draw at struggling Amiens after erasing a three-goal deficit only to concede a stoppage time-equaliser in Ligue 1 on Saturday. The result left PSG 13 points clear of second-placed Olympique de Marseille after manager Thomas Tuchel rested several regular starters ahead of Tuesday's first leg of their Champions League last-16 clash with Borussia Dortmund.
Union Berlin's Paul Jaeckel scored a 76th-minute winner to give his team a 1-0 victory at VfB Stuttgart on Sunday and send them two points clear at the top of the Bundesliga.
Pierre-Emerick Aubameyang scored twice as a rejuvenated Barcelona gave a football masterclass to inflict a humiliating 4-0 defeat on rivals Real Madrid on Sunday.
News of all that's transpired on and off the football fie
Juventus progressed to the Champions League last 16 after a Cristiano Ronaldo goal and a late header from substitute Alvaro Morata gave them a comeback 2-1 home win over Hungarians Ferencvaros on Tuesday.
Images from football matches played across Europe.
AC Milan, Villarreal and Nice reached the knockout stage of the Europa League after posting wins on Thursday in the penultimate round of the group stage.