A penalty from Kylian Mbappe in the 10th minute of stoppage time rescued Real Madrid, giving them an agonising 2-1 victory over local rivals Rayo Vallecano in LaLiga.
Nottingham Forest and Aston Villa reach the Europa League semi-finals, while Braga and Freiburg also advance in a dramatic night of European action.
Raphinha hat-trick fires Barcelona past Sevilla at top
Barcelona defeated Atletico Madrid, extending their lead in La Liga after Real Madrid's loss to Mallorca. Key goals from Lewandowski and Rashford secured Barcelona's victory, while Muriqi's late goal sealed Mallorca's win against Real.
Kylian Mbappe criticised Real Madrid's lack of hunger and consistency after their 4-2 Champions League loss to Benfica, saying champions must show desire every time as Real slipped into the playoffs.
Striker Robert Lewandowski scored a first-half penalty to give Barcelona a hard-fought 1-0 home win over Rayo Vallecano.
Spirited Rayo Vallecano hold Real Madrid to 0-0 draw
Real Madrid suffered a shock 2-0 loss and finished with nine men against Celta Vigo in LaLiga on Sunday.
Barcelona dropped their first points in LaLiga this season as Rayo Vallecano fought back to secure a 1-1 draw at home to the champions.
Real Madrid's struggles continued on Sunday as they battled to a 1-1 draw at Girona in LaLiga.
Barcelona closed the gap on their rivals Real Madrid, moving up to 28 points and pulling two clear of third-placed Villarreal.
Barcelona staged a thrilling second-half comeback to defeat Levante 3-2 away in LaLiga on Saturday, overcoming a two-goal deficit after a poor first-half display.
Rayo Vallecano came from behind to beat Real Madrid 3-2 on Monday with the champions failing to reclaim top spot in the standings after two consecutive games without a win.
Atletico celebrate anniversary with 3-1 comeback win over Mallorca
Real Madrid paid for defensive mistakes as they were held to a 3-3 draw at lowly local rivals Rayo Vallecano on Saturday.
Atletico had no shots on target until the referee awarded them the penalty for a handball by Getafe defender Omar Alderete which Sorloth netted with a low strike to the goalkeeper's left.
'We have to move on and go ahead, it's our job. It's an important situation for the club to advance in the competition and we want to do well to honour him.'
Spanish second division side Rayo Vallecano refused to turn up for the first day of group training due to a dispute with the club hierarchy over a pay cut for staff and players, a club source said on Monday.
Dani Olmo came off the bench in the second half to give Barcelona the spark they needed on his debut, against Rayo Vallecano.
A round-up of Saturday's action in LaLiga, Ligue 1 and Serie A
Barca will now visit seventh-placed Osasuna on Saturday before hosting Young Boys in the Champions League next week, when they will look to rebound following a 2-1 loss in their opening match at Monaco.
All soccer matches scheduled to be played in the Valencian region this weekend have been postponed, the Spanish football federation (RFEF) said on Thursday due to the deadly floods which have killed at least 95 people.
Gareth Bale made up for the absence of Cristiano Ronaldo by scoring twice to inspire Real Madrid to come from two goals down and win 3-2 at Rayo Vallecano on Saturday. Real managed to edge to the top of the table despite Ronaldo missing his first league game of the season with a muscle strain although they also suffered another scare before their Champions League semi-final next week with a suspected injury to Karim Benzema. Real had found themselves two behind within 14 minutes as Adrian Embarba scored from close range in the seventh minute before Rayo's Venezuelan striker Miku pounced on more poor defending from the visitors. Bale started the revival, heading in from a 35th minute corner before Zinedine Zidane's side drew level six minutes after the break through substitute Lucas Vazquez. Welshman Bale then completed the comeback nine minutes from time, collecting a misplaced pass from a Rayo defender before powering the ball past goalkeeper Juan Carlos.
Given that Bebe grew up in a orphanage and recalls playing youth football matches without eating, it is easy to see why he identifies with the proud yet humble club.
Late Griezmann strike ends Atletico's away day hoodoo
Robert Lewandowski and Raphinha both scored twice to help Barcelona thrash hosts Villarreal 5-1.
Gary Neville's disappointing start as Valencia coach continued when the ambitious Singapore-owned club drew 2-2 at home to lowly Rayo Vallecano in La Liga on Sunday, prompting more rumblings of discontent from the fans.
Real Madrid have reluctantly agreed to play their La Liga match at Rayo Vallecano at 1745 GMT on Monday, a day after the game was abandoned because of alleged lighting sabotage at Rayo's Estadio de Vallecas stadium.
Barcelona thrashed Real Betis 5-1 on Wednesday to book their spot in the Copa del Rey quarter-finals.
Stuttering Villarreal closed to within a point of the Champions League qualification places when a second-half Cedric Bakambu double secured a 2-1 comeback win at home to Rayo Vallecano in La Liga on Sunday.
Barcelona maintained their perfect start to La Liga with a 4-0 victory at Rayo Vallecano on Saturday, a Pedro hat-trick and a penalty save by Victor Valdes helping them to win a game that was not a simple as it looked.
IMAGES from football matches played across Europe on Wednesday.
Lionel Messi created a goal and scored another as Barcelona came from behind to beat struggling Rayo Vallecano 3-1 at home on Saturday and stay seven points clear at the top of La Liga.
Real Madrid superstar Cristiano Ronaldo has played down an injury suffered during his side's 3-0 win over Villarreal in their La Liga match on Wednesday, saying that he is in a good condition.
Stuttering Spanish champions Real Madrid returned to winning ways in La Liga but were well short of their scintillating best in a laboured 2-0 victory at lowly city rivals Rayo Vallecano on Monday.
La Liga leaders Real Madrid were held to a frustrating 1-1 draw at lowly city rivals Rayo Vallecano on Sunday as Joselu's early strike was cancelled out by Raul de Tomas' penalty, a result that could spice up the title race with surprise package Girona.
Lionel Messi took his senior career goals tally to 301 as he scored twice in Barcelona's 5-0 victory at Rayo Vallecano which put them three points clear at the top of La Liga.
Barcelona kept Real Madrid's La Liga title celebrations on hold for a few days at least with a crushing 7-0 victory at Rayo Vallecano on Sunday after Real had cruised to a 3-0 home win over Sevilla.
Unconvincing Real Madrid survived a huge scare at rock bottom Rayo Vallecano when they conceded two quickfire second-half penalties but held on under severe pressure to secure a nervy 3-2 victory in La Liga on Saturday.
Toni Kroos netted his first for Real Madrid and was hailed as the best player on the pitch by his coach as the hosts tore apart Rayo Vallecano 5-1 in La Liga on Saturday to extend their winning streak to 13 games.