Inter Milan face Barcelona, Tottenham Hotspur and PSV Eindhoven in Group B which features three former European champions.
Former Inter Milan, Liverpool and Chelsea manager Rafael Benitez will return to Italy to take charge of Serie A club Napoli.
An estimated 10,000 Napoli supporters, including the team's most famous player Diego Maradona, are expected to make the trip to the Spanish capital for the first competitive meeting with Real Madrid since the 1987.
Manchester City spent more than 180 million pounds ($223.58 million) -- more than the combined amount paid by the other 19 English top-flight clubs in a relatively quiet window.
A summary of Saturday's action in LaLiga, Bundesliga and Serie A.
Napoli booked a clash with AS Roma in the Italian Cup semi-finals after a late instinctive Gonzalo Higuain backheel lifted Rafael Benitez's side to a 1-0 win over Lazio on Wednesday.
Napoli striker Gonzalo Higuain scored twice to put them top of Serie A with an extraordinary 2-1 win over Inter Milan who twice hit the woodwork in stoppage time after playing the entire second half with 10 men on Monday.
Senad Lulic scored a late goal to give Lazio a 1-0 win at Napoli which sent them into the Coppa Italia final and added to Rafael Benitez's problems on Wednesday.
Barcelona top the LaLiga standings with 15 points, four ahead of Real Madrid and Villarreal. Girona are seventh on seven points.
Juventus have completed the signing of Argentina forward Gonzalo Higuain from Napoli.
Liverpool received a relatively kind draw for the group stage of this year's Champions League
Napoli rediscovered their scoring touch as they brushed aside Inter Milan 3-0 on Friday, sending their opponents' new coach Stefano Pioli back to the drawing-board.
Jose Callejon took advantage of Napoli's numerical advantage in the 48th minute of the playoff round second leg tie, handing them an away goal which, added to their 2-0 win from the first leg, effectively ended Nice's challenge as it left the French side needing to score four goals.
Liverpool failed to muster a single shot on target in a Champions League game for the first time since a 1-0 defeat to Benfica in February 2006.
Gonzalo Higuain scored his 30th league goal of the season but was later sent off and had to be restrained by his team mates as Napoli lost 3-1 at Udinese on Sunday, severely denting their Serie A title hopes.
Two goals in three devastating second-half minutes helped Napoli reach the Italian Cup final on Wednesday with a 3-0 win over AS Roma in the second leg of their semi-final in Naples, to clinch the tie 5-3 on aggregate.
Gonzalo Higuain has led Napoli's challenge for their first Serie A title since 1990 with a remarkable 26 goals in 28 league games, yet the fiery Argentine does not seem to have enjoyed a single moment of it. Higuain, an out-and-out striker who can safely be described as an old-fashioned number nine, stomps around the field with an expression that suggests he is carrying the whole world on his shoulders. There is always something for the 28-year-old to gesticulate angrily about, whether it be a refereeing decision, a team mate failing to pass him the ball or his coach deciding to substitute him. In his last outings, he kicked a water bottle over in disgust after being substituted at Fiorentina and then failed to join his team mates in saluting the crowd following Saturday's 3-1 win over Chievo, despite scoring in both games. His goal celebrations invariably involve thumping his chest and seem to be more an act of defiance than a show of joy.
Barcelona thrashed Real Betis 5-1 on Wednesday to book their spot in the Copa del Rey quarter-finals.
Napoli jumped to second place in Serie A thanks to a laboured 1-0 win at lowly Cagliari while fellow title hopefuls Inter Milan suffered a 1-0 defeat at Parma in Monday's late game.
The Polish player was driving through the Varcaturo district of Naples at around 2 am when the motorbike blocked the road and forced him to stop, the report said.
Chelsea named former Napoli boss Maurizio Sarri as the new head coach on a three-year term on Saturday, a day after parting ways with another Italian manager Antonio Conte.
Stand-in defender Vlad Chiriches atoned for an early blunder by scoring his first Serie A goal to help Napoli come from behind and beat Chievo 3-1 in Serie A on Saturday, putting them level at the top with Juventus.
Frustrated AC Milan missed the chance to seize top spot in Serie A when they were held to a 1-1 draw by Napoli at the San Siro on Sunday.
Barcelona joined Real Madrid, Atletico and Real Sociedad in the semi-finals, with the draw set to take place on Wednesday.
Atalanta forward German Denis took advantage of shocking defending by Napoli to score twice in a 3-0 win over Rafael Benitez's exasperatingly inconsistent team on Sunday.
Napoli have agreed to buy Spain centre back Raul Albiol from Real Madrid, the Serie A club said on Sunday.
'I understood that if I dedicated myself solely to coaching, I could get much better at it'
Napoli won their first major title since the Diego Maradona era, denied Serie A champions Juventus the double and handed their captain Alessandro Del Piero an unhappy end to 19 seasons at the club by beating the Turin side 2-0 in the Italian Cup final on Sunday.
Lewandowski strike gives Barcelona 1-0 win over Alaves
Striker Edinson Cavani scored a superb hat-trick to give Napoli a 3-1 home win over defending Serie A champions AC Milan on Sunday.
Carlo Ancelotti's side held a two-goal lead at halftime thanks to strikes from Dries Mertens and Kostas Manolas, but Balotelli pulled one back as Brescia rallied after the break.
Napoli went down 3-1 at home to RB Leipzig, Arsenal and AC Milan enjoyed comfortable away wins, and Borussia Dortmund's Michy Batshuayi scored twice to secure a 3-2 victory in Europa League last 32, first leg action
All the action from football matches played in Europe on Wednesday
Napoli suffered an agonising exit from the Champions League after beating Premier League leaders Arsenal 2-0 on Wednesday.
Napoli squandered a two-goal halftime lead, then scored two late goals to beat nine-man AC Milan 4-2 in a stormy Serie A match which saw eight other players booked on Saturday.
Barcelona's Ferran Torres scored twice to help secure a late 4-2 comeback win at Atletico Madrid in a pulsating LaLiga clash on Sunday.
Arsenal manager Arsene Wenger has told his players to watch out for Napoli's quickfire counter-attacks when the two high-flying sides meet at the Emirates Stadium in Champions League Group F on Tuesday.
Fiorentina said in a statement that Edoardo Bove was under sedation at the Careggi University Hospital in Florence having lost consciousness during the match.
Ibrahimovic was forced off with a muscle problem with 11 minutes remaining, and the Swede was pictured sitting on the bench with an ice pack strapped to the back of his left leg.
'It is over and I can clearly state without fear of being contradicted that Maradona has never been a tax evader.'
