Vinicius Jr came off the bench to score once and set up another goal to steer champions Real Madrid to a 4-1 fightback victory over Espanyol.
Barcelona thrashed Real Betis 5-1 on Wednesday to book their spot in the Copa del Rey quarter-finals.
Barcelona joined Real Madrid, Atletico and Real Sociedad in the semi-finals, with the draw set to take place on Wednesday.
Football action from across Europe in matches played on Saturday
A summary of Saturday's action in the Serie A, Ligue 1 and Bundesliga
Lewandowski strike gives Barcelona 1-0 win over Alaves
Images from Europa League matches played on Thursday.
Napoli kept alive their hopes of advancing from Group C after Lorenzo Insigne, Victor Osimhen and Matteo Politano secured a 3-0 home win over Legia Warsaw.
Barcelona top the LaLiga standings with 15 points, four ahead of Real Madrid and Villarreal. Girona are seventh on seven points.
Cristiano Ronaldo was involved in all three of his team's goals as Juventus came from behind to beat Napoli 3-1 in a Serie A top-of-the-table clash on Saturday to maintain their perfect start to the season.
Fiorentina said in a statement that Edoardo Bove was under sedation at the Careggi University Hospital in Florence having lost consciousness during the match.
All the action from football matches played in Europe on Wednesday
Barcelona reached the Champions League quarter-finals for the first time in four years
IMAGES from Europa League matches played on Thursday.
Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.
Napoli did not travel to Turin for the match on October 4, saying their local health authority (ASL) had told the players to stay at home after two members of their squad tested positive for COVID-19.
A round-up of Wednesday's action in the UEFA Champions League.
In the third-tier Europa Conference League, English Premier League club Leicester City will face Danish side Randers and Scottish club Celtic will take on Norwegian champions Bodo/Glimt in the knockout playoff round.
Napoli maintained their two-point advantage at the top of Series with a 2-0 victory at Lazio on Wednesday in a game suspended due to racist chanting as Juventus beat Genoa 1-0 to break a club record for consecutive league wins in a single season.
Second-placed Napoli comfortably overcame the absence of suspended top scorer Gonzalo Higuain to brush aside bottom-of-the-table Verona 3-0 in Serie A on Sunday. Napoli stayed points six behind leaders Juventus, who won 2-1 at AC Milan on Saturday, with six matches each to play, and remain outsiders to win their first title since 1990 despite the win. Higuain, who has led Napoli's challenge with 30 goals, will miss the next three games as he completes a four-match ban for his sending-off and furious reaction in last week's 3-1 defeat at Udinese. Fiorentina's recent dismal run continued when they lost to their smaller Tuscan neighbours Empoli for the first time since 1997, leaving them fifth in the table. Juventus have 76 points from 32 games with Napoli on 70, AS Roma on 63, Inter Milan on 58 and Fiorentina on 56. Napoli hit the post twice and had a goal disallowed before Manolo Gabbiandini headed them in front in the 33rd minute, his fifth goal in only seven starts this season, after Verona goalkeeper Pierluigi Gollini parried Jose Callejon's shot.
Serge Gnabry scored twice as Bayern Munich beat Chelsea 3-0, while Antoine Griezmann's second-half equaliser handed Barcelona a vital away goal and earned them a 1-1 draw at Napoli in their Champions League last 16, first leg on Tuesday.
Ivan Toney, once Brentford's lynchpin in attack, has moved to Al-Ahli for 40 million pounds ($52.50 million).
Napoli coach Walter Mazzarri has laughed off talk that his side are favourites ahead of Tuesday's UEFA Champions League last-16 first leg against Chelsea in Naples.
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Messi's damning assessment of the team came home to roost when the season re-started after the coronavirus stoppage and Barca surrendered the league title to Real Madrid, prompting the captain to launch a new tirade against the team.
Images from the football matches played across Europe on Wednesday.
Juventus rehire Allegri.
AC midfielder Franck Kessie scored from a penalty to give AC Milan a 2-2 draw away to Napoli in Serie A on Sunday, sparing the blushes of his goalkeeper Gianluigi Donnarumma whose mistakes provided the hosts with both their goals. Sevilla closed in on Champions League qualification by beating struggling Real Mallorca 2-0 at home to open up a nine-point gap in the race for fourth spot in La Liga.
London sides Tottenham Hotspur and Arsenal made winning starts as did fellow Premier League club Leicester City.
'It is over and I can clearly state without fear of being contradicted that Maradona has never been a tax evader.'
Juventus raced into a 2-0 halftime lead after Napoli goalkeeper Alex Meret was sent off in the 25th minute. The visitors then had Pjanic dismissed and Napoli's Jose Callejon pulled one back before Insigne let the Turin side off the hook.
Arsenal might be struggling in the Premier League but they are 100 per cent in Group B of the Europa League
Real Madrid defender Nacho was the unlikely hero as they snatched a 1-0 win at Real Valladolid on Sunday to capitalise on Barcelona's defeat at Valencia this weekend and move three points clear of their rivals at the top of La Liga. Serie A leaders Juventus suffered a shock 2-1 defeat at Napoli on Sunday, with coach Maurizio Sarri returning to his former club for the first time, though Cristiano Ronaldo still managed to score for an eighth league game in a row for the visitors.
Inter Milan face Barcelona, Tottenham Hotspur and PSV Eindhoven in Group B which features three former European champions.
Defender Hugo Campagnaro, who survived a fatal car crash in his native Argentina in June, scored the decisive goal as Napoli won 3-1 at 10-man Cesena in their opening Serie A match of the season on Saturday.
An estimated 10,000 Napoli supporters, including the team's most famous player Diego Maradona, are expected to make the trip to the Spanish capital for the first competitive meeting with Real Madrid since the 1987.
Former Inter Milan, Liverpool and Chelsea manager Rafael Benitez will return to Italy to take charge of Serie A club Napoli.
The following is the draw for the Champions League last 16 which was held in Nyon on Monday:
Liverpool received a relatively kind draw for the group stage of this year's Champions League
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