Mbappe fires Real Madrid to the summit, Bayern lose at home and Dortmund stay in the title hunt.
IMAGES from football matches played across Europe on Sunday
A round-up of Tuesday's action in the UEFA Champions League.
Villarreal fought back to shock Barcelona 3-2 on Sunday, handing the LaLiga champions their first league defeat since late December.
Saturday's draw left Spain third in Group E with two points and needing a win against Slovakia on Wednesday to guarantee their place in the next round of Euro 2020.
Spain are still favourites to finish top of Group E above Sweden, Poland and Slovakia but, after struggling to break down conservative sides such as Georgia and Greece in March, they know coming first will not be a procession.
Spain claimed the biggest win of the tournament with a 5-0 thrashing of Slovakia in their final European Championship Group E match on Wednesday to finish second in the group and set up a last-16 clash with Croatia in Copenhagen.
Harry Kane scored twice in his first league appearance in front of a home crowd to steer champions Bayern Munich to a 3-1 victory over Augsburg.
Villarreal set up a King's Cup semis against Barca after Gerard Moreno gave them a 1-0 win
Villarreal's struggles in the Spanish league continued with a 2-1 loss at Athletic Bilbao, with striker Gerard Moreno not finishing the game because of an injury.
'We created so many chances and simply weren't effective with them. In fact we created a rainbow of different chances and there are just some days when the ball refuses to go in.'
Real Madrid rested Cristiano Ronaldo and suffered a fifth Liga defeat of the season as Espanyol's Gerard Moreno struck late for a 1-0 win over the Spanish and European champions.
'It wasn't easy, but I called him last night (Sunday) and we had a difficult and tough conversation. I feel bad as he's a player who has always been at the top level and has a future with the national team.'
IMAGES from the football matches played across Europe on Sunday.
Spain prevail in shootout against gallant 10-men Swiss
Gerard Moreno -- who scored against Manchester United before the Europa League final in Gdansk went to penalties -- rescued Unai Emery's side in the 73rd with a side-foot finish after a back-heel from Boulaye Dia.
Germany suffered their first home defeat in a World Cup qualifier in 20 years
Alvaro Morata spurned Spain's best opportunity in a dominant first half display from Luis Enrique's side on a scorching evening at Seville's La Cartuja stadium in Group E when he missed the target from inside the area after a defensive slip.
After a tense encounter finished 1-1 following extra time, Villareal's Rulli stepped up after every on-field player scored their spot kicks and he comfortably beat Spaniard De Gea
Real Madrid saw off a stirring Chelsea fightback to book their place in the Champions League semi-finals following a 3-2 defeat after extra time in a scintillating second leg at the Santiago Bernabeu on Tuesday to go through 5-4 on aggregate.
Holders Chelsea made light of their off-pitch problems to reach the Champions League quarter-finals by beating Lille 2-1 away on Wednesday to complete a 4-1 aggregate victory.
Karim Benzema's hat-trick earned Real Madrid a 3-1 win at reigning European champions Chelsea in their Champions League quarter-final first leg on Wednesday. In another quarter-final match, Villarreal stunned six times European Cup winners Bayern Munich 1-0.
Images from the Euro 2020 Qualifiers played on Monday
Real were smarting from a surprise 1-1 draw at struggling Elche in their last match and were missing captain Sergio Ramos, who was out with a stomach bug.
Images from the Nations League matches.
Atletico Madrid won the La Liga title for the first time since 2014
Images from La Liga matches played on Monday.
Images from UEFA Europa League semi-finals played on Thursday.
Bruno Fernandes and Edinson Cavani scored twice each as Manchester United took a giant step towards the Europa League final with a 6-2 drubbing of AS Roma in their semi-final first leg at Old Trafford on Thursday.
Third-placed Inter Milan scored twice in the last six minutes through Stefan De Vrij and Alessandro Bastoni to snatch a 2-1 win at Parma in Serie A on Sunday despite a subdued display. The scarcely-deserved victory left Inter eight points behind leaders Juventus and four adrift of second-placed Lazio with 10 games each to play.
Images from football matches played in La Liga and Serie A in Spain and Italy on Wednesday.
IMAGES from the Europa League matches played on Thursday
IMAGES from Europa League matches played on Thursday.
IMAGES from Europa League matches played on Thursday.
Paris Saint Germain's Neymar, Laywin Kurzawa and Leandro Paredes as well as Marseille's duo of Dario Benedetto and Jordan Amavi were given their marching orders after rival players threw punches and kicks at each other.
IMAGES from the Europa League matches played on Thursday
Unai Emery's Villarreal were much improved in the second half and had spurned numerous chances before Moreno's leveller.
Ousmane Dembele's late strike rescued a 1-1 draw for champions Barcelona at Atletico Madrid but Sevilla moved top with a 1-0 win over Real Valladolid. European champions Real Madrid were humiliated in a 3-0 defeat at Eibar.
Images from the UEFA Champions League matches played on Wednesday.
Cristiano Ronaldo shrugged off the boos of his own supporters to fire Real Madrid to a 3-0 win over Real Sociedad on Sunday.