A controversial Gerard Deulofeu strike sent Barcelona on their way to a comfortable 2-0 victory over Malaga on Saturday as they stretched their lead at the top of La Liga.
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Valencia recaptured fourth place in La Liga from Sevilla when Sofiane Feghouli scored the pick of the goals in a 4-0 stroll at home to second-from-bottom Granada on Monday.
Marcelino dismissed but Valencia keep pressure on Barcelona
Sevilla became surprise Liga leaders on Sunday after beating visiting Celta Viga 2-1 while champions Barcelona drew 1-1 at Valencia thanks to another Lionel Messi strike but are still without a victory in their last four league games.
Gary Neville's disappointing start as Valencia coach continued when the ambitious Singapore-owned club drew 2-2 at home to lowly Rayo Vallecano in La Liga on Sunday, prompting more rumblings of discontent from the fans.
Nani, who was recently crowned European champion with Portugal, wants to help bring the good times back to new club Valencia.
Under-fire Rafa Benitez said Real Madrid needed to be more consistent and also accused his players of easing off in games ahead of Sunday's La Liga clash with his former club Valencia. The Spaniard is the most successful coach in Valencia's history. He led them to La Liga titles in 2002 and 2004, when he also won the UEFA Cup, and is sure of a warm welcome when he walks out at the Mestalla.
The result also means second-placed Real Sociedad can reclaim top spot if they beat Eibar on Sunday.
Pedro hit a first-half hat-trick as Barcelona cruised into the last 16 of the King's Cup with a 8-1 second leg demolition of lower league Huesca at the Camp Nou on Tuesday.
Portugal international Goncalo Guedes fired Valencia into the lead in the 35th minute with a thumping shot from inside the area which was too powerful for Madrid goalkeeper Keylor Navas.
Valencia turned up the heat on Atletico Madrid in the fight for third place in La Liga when a 3-0 derby victory at home to Levante on Monday lifted the Singapore-owned club to within a point of the champions with seven games left.
Antoine Griezmann scored twice off the bench as Atletico Madrid sealed a place in the King's Cup quarter-finals with a 3-0 win at home to Rayo Vallecano on Thursday while Valencia also advanced with victory by the same scoreline at Granada.
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Angry Barcelona coach Luis Enrique blamed stupid mistakes after the La Liga pacesetters threw away a two goal lead to draw 2-2 at home to Deportivo La Coruna on Saturday. Barca have drawn their last two games in La Liga and could see Atletico Madrid draw level with them if they beat Athletic Bilbao on Sunday, ahead of their trip to the Club World Cup in Japan next week.
RB Leipzig marked their first appearance in the Champions League knockout round with a deserved 1-0 victory at last season's runners-up Tottenham Hotspur
A summary of Tuesday's Group stage matches in the UEFA Champions League.
Arsenal's Pierre-Emerick Aubameyang struck a vital late goal to seal a 3-1 win over Valencia on Thursday and give his side breathing space for the second leg of their Europa League semi-final in Spain next week.
A Paco Alcacer header gave Valencia a 2-2 draw in a highly charged La Liga clash against third-placed Real Madrid who had taken the lead with eight minutes remaining on Sunday.
Alvaro Negredo struck in stoppage-time as stuttering Valencia won 2-1 against his former club Sevilla on Sunday to earn coach Pako Ayesteran victory in his first home game in charge since succeeding Gary Neville.
A summary of Saturday night's matches in the Euro 2020 qualifiers.
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Real Madrid's stuttering season continued as they were reduced to 10 men and then slumped to an 11th La Liga defeat of the campaign by going down 3-1 at Real Sociedad.
Alexandre Lacazette's free-kick sent Arsenal into the Europa League semi-finals with a comfortable 1-0 win away over Napoli, while Chelsea beat Slavia Prague 4-3 in a roller-coaster game, helped by a Pedro brace.
Bastia game abandoned after fans attack Lyon players
New Valencia coach Gary Neville remains without a La Liga win after his side twice recovered from a goal down to rescue a fortunate 2-2 draw at home to Getafe on Saturday.
Espanyol's Felipe Caicedo came off the bench and netted two late goals to secure a 2-0 win at home to 10-man Valencia on Tuesday that sent the Barcelona-based club through to the King's Cup quarter-finals 3-2 on aggregate.
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A summary of Wednesday's matches in the UEFA Champions League.
An Aaron Ramsey strike and a Kalidou Koulibaly own goal gave Arsenal a 2-0 victory over Napoli in the first leg of their Europa League quarter-final, while Chelsea beat a stubborn Slavia Prague 1-0.
A round-up of Wednesday's night's UEFA Chmpions League matches.
Chelsea struck the woodwork twice but could not find a breakthrough in an entertaining 0-0 Champions League draw at Dynamo Kiev on Tuesday that left everything to play for in Group G.
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European heavyweights Barcelona, Bayern Munich, Juventus and Paris St Germain all maintained their leads and Benfica toppled Sporting Lisbon.
Manchester United flirted with calamity before coasting into the Europa League last 16 as debutant Marcus Rashford helped them overcome an early blow with two goals in a 5-1 home victory over Midtjylland on Thursday.
Lionel Messi marked his 300th La Liga appearance with a record-equalling hat-trick and an assist for Neymar as Barcelona stayed hard on the heels of leaders Real Madrid with a 5-0 romp at home to Levante on Sunday.
Barcelona left it late to snatch a 1-0 win at Valencia on Sunday after Atletico Madrid's 2-0 victory at home to Deportivo La Coruna was overshadowed by the death of a visiting fan hours before kickoff.
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Goals from Jan Vertonghen and Jermain Defoe left Tottenham Hotspur on the cusp of the Europa League knockout stages as four other clubs maintained perfect starts on Thursday.
Images from the Champions League matches played on Wednesday