Valencia, who lifted the trophy on their last appearance in the showpiece match in 2008, will meet 30-times winners Barca in the final on May 25 at Betis' Benito Villamarin stadium.
News of all that's transpired on and off the football field
Lionel Messi said he will not be part of Argentina's squad for the Paris Olympics.
Brazil have won the Copa America every time they hosted the tournament
Six people survived, including three members of the club, en route to the Copa Sudamericana final against local side Atletico Medellin, the biggest game in Chapecoense's history.
The 2015 and 2016 Copa champions took the lead late in the first half with a towering header from midfielder Erick Pulgar.
Peru beat Paraguay 2-0 at the Copa America on Friday to ensure they finished in third place.
Peru moved into the semi-finals of the Copa America in dramatic fashion on Friday by beating Paraguay 4-3 on penalties after the two sides drew 3-3 over 90 minutes in an action-packed encounter in Goiania.
Argentina captain Lionel Messi pulled his side level in the 57th minute after a handball by Paraguay's Ivan Peris which no-one on the pitch appealed for but was spotted by a VAR review.
Gabriel got the winning kick for Brazil after Gustavo Gomez and Derlis Gonzalez missed for the visitors. Roberto Firmino pulled his spot kick wide for the hosts.
Argentina's Lionel Messi has unfinished business going into the Centenary Copa America that is being staged in the United States with the Barcelona star keen to help his nation capture a first major title in 23 years.
Argentina host Chile at the Monumental stadium in Buenos Aires on September 5 before facing Colombia five days later in Barranquilla.
Chile's euphoria at reaching the final of the Copa America was tempered by the reminder that every time they have been in this position before they have finished as runners-up.
Brazil's Gabriel Jesus made one goal, scored another and was sent off in the second half as they beat Peru 3-1 to win the Copa America for the ninth time.
Barcelona pulled off a stirring comeback to overturn a two-goal deficit and reach the Copa del Rey final, beating Sevilla 3-0 after extra-time in Wednesday's semi-final second leg, to go through 3-2 on aggregate.
A summary of Wednesday's Champions League first leg quarter-finals between Barcelona and Dortmund and Real Madrid, and Paris St Germain and Aston Villa.
Lionel Messi trained alongside his Argentina team-mates at the Copa America Centenario as he targets a return from injury in his team's second Group D game against Panama. Messi, who has been nursing a sore back after sustaining an injury in a friendly against Honduras last month, has trained separately under the supervision of team medical staff since arriving in the United States. However the 28-year-old Barcelona superstar took part in a full training session on Wednesday at the University of Illinois campus, two days after sitting out Argentina's opening 2-1 victory over Chile in Santa Clara on Monday.
The United States' bid for a fourth consecutive CONCACAF Nations League title came to a stunning end
Five-time world player of the year Lionel Messi of Argentina, Chile's Alexis Sanchez and Brazilian Dani Alves were among the big names in the final rosters announced on Monday for next month's Copa America Centenario.
Uruguay eliminated Mexico from the Copa America Tuesday to set up a mouth-watering quarter-final clash with Argentina, while Chile finished top of Group C after a 1-0 win over Peru.
Chile face Argentina in Sunday's Copa America final for the right to call themselves South America's dominant team but perhaps an even bigger question for football fans the world over regards whether Lionel Messi can finally win a major international title. The Barcelona forward has won every trophy possible with the Spanish club but he has lost three finals with Argentina, including in 2014 World Cup Final in 2014 and the Copa America last year. Sunday's game against Chile in New Jersey gives Messi a chance to end both his personal hoodoo and that of Argentina, who have not won a major title since lifting the Copa America in Ecuador in 1993.
Next year's Copa America in Chile will give Brazil the chance to bury the ghosts of their miserable World Cup, the president of the country's soccer federation said.
Brazil overwhelmed Peru with three goals in a superb first half to set up a crushing 5-0 victory on Saturday and cruise into the Copa America quarter-finals.
All soccer matches scheduled to be played in the Valencian region this weekend have been postponed, the Spanish football federation (RFEF) said on Thursday due to the deadly floods which have killed at least 95 people.
Paraguay coach Ramon Diaz has resigned after the team's elimination in the group phase of the Copa America Centenario, Paraguayan FA (APF) sources said on Sunday.
Neymar took part in team training and will join the Al-Hilal squad for their Asian Champions League trip to UAE Pro League club Al-Ain after recovering from a serious knee injury, the Saudi Pro League club said.
Argentina can look forward to a mouthwatering Copa America semi-final clash with Brazil after delivering a much-improved display to beat Venezuela 2-0 in the quarter-finals in their first game at the Maracana since losing the 2014 World Cup final.
Stakeholders are confident the Spanish league season can resume in mid-June in closed stadiums without spectators, with fans not expected to be able to return to grounds until 2021.
Thiago Silva and Roberto Firmino scored either side of halftime to fire Brazil to a 2-1 win over Venezuela at the Copa America.
Kaka has dropped out of the Brazil squad for the Centenary Copa America due to injury and will be replaced by Paulo Henrique Ganso, the Brazilian Football Confederation (CBF) said.
Brazil forward Neymar has been ruled out of the Copa America after suffering a serious ankle injury in a 2-0 friendly win over Qatar.
The 'Noodle' has broken again with Angel Di Maria injured during a third consecutive major tournament playing for Argentina at the end of a busy club season.
South America's top football competition kicked off on Thursday amid fireworks and razzmatazz.
Estudiantes scored a a come-from-behind 2-1 victory over Cruzeiro to lift their fourth Copa Libertadores title on Wednesday.
IMAGES from soccer matches played across Europe on Sunday.
Barcelona thrashed Real Betis 5-1 on Wednesday to book their spot in the Copa del Rey quarter-finals.
An early goal from Lautaro Martinez and a late second from Sergio Aguero gave Argentina a 2-0 win over Qatar on Sunday, a deserved victory that takes them into the Copa America quarter-finals.
Copa America kicks off in Chile on Thursday as a widening US-led investigation lifts the lid on rampant corruption among the sport's top officials.
Argentina shrugged off the injury absence of Lionel Messi to launch their Copa America Centenario campaign with a 2-1 defeat of defending champions Chile in Santa Clara, United States on Monday. Goals from Angel Di Maria and Ever Banega secured a deserved three points for Argentina, who exacted sweet revenge for their defeat to the Chileans in last year's Copa America final. Chile substitute Jose Fuenzalida scored an injury time consolation for the holders. The Argentines will now be firm favorites to progress to the quarter-finals as Group D winners with games against Panama and Bolivia to come. Injured Argentina captain Messi watched from the substitutes' bench at Levi's Stadium after failing to recover in time from a sore back suffered in a friendly win over Honduras last month. But the Barcelona superstar's absence was barely noticeable, with Nicolas Gaitan slotting into Argentina's attack and making an instant impression, hitting the woodwork with a header after only two minutes.
Barcelona came from an early goal down to beat Real Madrid 5-2 in the Spanish Super Cup final on Sunday