Zlatan Ibrahimovic bagging four goals, while Juventus and Bayern Munich preserved their leads and FA Cup holders Arsenal were dumped out of the competition.
The former Paris St Germain manager will be presented on Wednesday and will replace Jose Mourinho who left at the end of last season to join Chelsea.
Chelsea, Bayern Munich, Real Madrid and Juventus consolidated their top-flight leads at the weekend while Paris St Germain proved too strong for Ligue 1 leaders Olympique Marseille.
News of all that's transpired on and off the football field
Playmaker Kaka breathed new life into struggling AC Milan by scoring twice and 18-year-old Bryan Cristante claimed his first professional goal as they beat Atalanta 3-0 on Monday for only their fifth league win of the season.
News of all that's transpired on and off the football field
Barcelona lost for the second straight La Liga game in a 1-0 home reverse against Celta Vigo but there was no such trouble for Manchester City, who beat 10-man Manchester United 1-0 thanks to Sergio Aguero.
The Hong Kong Football Association were left red-faced and out of pocket after only managing to sell half the tickets for Tuesday's glamour friendly against Argentina to mark their centenary.
Neymar shrugged off some rough tackling and a missed penalty to score a brilliant solo goal as he led Brazil to a 3-0 win over Paraguay that moved them within sight of the 2018 World Cup finals on Tuesday.
Chelsea returned to their early-season form to open up a five-point lead in the Premier League, Cristiano Ronaldo and Lionel Messi continued to make mincemeat of La Liga defences and Juventus extended their lead in Serie A. In France, Olympique Lyonnais retained top spot with a 2-0 win at RC Lens.
Real Madrid edged past Sporting Lisbon 2-1, while Juventus came from behind to secure a 3-1 win at Sevilla and Borussia Dortmund crushed Legia Warsaw 8-4 to set a record for the most goals scored in a Champions League match.
A weekend of surprise results across Europe's big leagues saw Bayern Munich's unbeaten run come to an end, Napoli knocked off top spot in Serie A and Manchester City toppled in the Premier League where Leicester City are the new leaders.
A summary of Wednesday's matches in the UEFA Champions League.
US Open champions Marin Cilic and Serena Williams kicked off their China Open campaigns with straight sets victories against battling underdogs on Monday, but Rafael Nadal suffered defeat in a rare doubles outing on his return from injury.
Chelsea reached the Champions League knock-out stage on Tuesday despite a 1-0 defeat by Basel in Group E after a late Mohamed Salah goal shocked the 2012 title winners, with Jose Mourinho saying they deserved to lose. Barcelona, without Lionel Messi but already into the last 16, went two goals down in Amsterdam but looked a different side in the second half after Ajax's Joel Veltman was sent off.
Images from the UEFA Champions League matches played across Europe on Wednesday
Dutch teenager Max Verstappen is a rare talent comparable to the late Ayrton Senna, according to Red Bull's Formula One consultant Helmut Marko.
An inspired performance from Douglas Costa helped Brazil to a 3-0 win over Peru on Tuesday and lifted them into third place in the South American qualifying group for the 2018 World Cup in Russia.
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