It was Messi's 56th converted penalty in La Liga and saw him draw level with Hugo Sanchez as the league's second-top penalty taker, behind record holder Cristiano Ronaldo on 61.
Cristiano Ronaldo has received an offer to leave Real Madrid and join Italian champions Juventus, a source close to the player said.
Gagan Narang was tied 5th with Jozef Gonci of Slovakia after both shot an identical score of 697.7
Lionel Messi was back in scoring business for Barcelona on Sunday, leading them to a resounding 4-0 win at home against Villarreal in a near-perfect La Liga opener for the Catalans under new coach Ronald Koeman.
Indian shooter Prakash Nanjappa will compete at the Rio 2016 Olympic Games three years after being told by doctors that his career was over. In 2013, he suffered 'a type of stroke or paralytic attack' at a world cup event in Granada, Spain, and was diagnosed with a type of paralysis known as Bell's palsy, chiefly on the right side of his face. "The scariest part was when the doctor said I would have to stop shooting," Nanjappa said. "That motivated me to come back.
India's Prakash Nanjappa has earned a quota place for the 2016 Rio Olympics after finishing eighth in the finals of 50-metre men's pistol event at the ISSF World Cup in Gabala, Azerbaijan.
Striker Aduriz opened the scoring in the sixth minute at the San Mames with a trademark header before midfielder Garcia, who joined from Atletico Madrid last month, nodded in a second in the 24th minute.
Real Madrid forward Cristiano Ronaldo ended his early-season drought in emphatic style when he hit five goals in a 6-0 romp at Espanyol on Saturday to become the club's record scorer in La Liga.
Cristiano Ronaldo answered his critics with a hat-trick as Real Madid came from behind to win 4-1 at Alaves and provisionally go three points clear at the top of La Liga.
Barcelona coach Luis Enrique defended his team's integrity on Friday after a week in which his players were criticised by the highest powers in Spanish soccer following last week's dramatic 3-2 win at Valencia.
Atletico Madrid's Brazilian striker Diego Costa scored twice as they came from behind to beat Levante 3-2 at home on Saturday to go three points clear at the top of La Liga.
Real Madrid keeper Iker Casillas believes the European champions have a side with the potential to be one of the all-time greats and it will be with likely trepidation that an off-colour Liverpool visit the Bernabeu on Tuesday.
Atletico Madrid secured a berth in the Champions League group stage for next season and Deportivo La Coruna narrowly escaped relegation when they came from two goals down to draw 2-2 at champions Barcelona on the final day in La Liga on Saturday.
The draw interrupted a run of four straight league wins for Zinedine Zidane's side and left them second on 67 points after 31 games, three behind leaders Atletico who thrashed Eibar 5-0 earlier in the day.
Real Madrid were dumped out of the Copa del Rey at the quarter-final stage on Thursday after losing 4-3 at home to Real Sociedad, while record 30-times winners Barcelona were sent crashing out of the Copa del Rey in a 1-0 defeat at Athletic Bilbao.
Cristiano Ronaldo kept up his rich La Liga scoring form as Real Madrid beat Villarreal 2-0 on Saturday to move up to fourth.
India's shooters failed to impress on the third day of competitions in the 51st Shooting World Championship as trap ace Manavjit Singh Sandhu missed out on a final berth by a whisker while Rahi Sarnabot and Anisa Sayyed disappointed in women's 25 metres pistol, in Granada.
'Critics will always appear because people don't like it when the same people win all the time, but I'm sure Pep is going to win'
Real Madrid midfielder Gareth Bale damaged a calf muscle in his left leg during Tuesday's 4-0 Champions League Group A victory at home to Shakhtar Donetsk, tests confirmed on Thursday.
Real Madrid coach Zinedine Zidane shrugged off his first setback since taking over from the sacked Rafa Benitez after his new team could only manage a 1-1 draw at Real Betis in La Liga.
Gagan Narang missed out on an Olympic quota by just one place as he finished sixth in the final of the men's 50-metre rifle prone while Prakash Nanjappa and Jitu Rai narrowly missed out on the final of the 10-metre air pistol at the 51st Shooting World Championships in Granada.
A summary of sports stories from across the globe
Real Madrid tightened their grip on top spot by beating Alaves 3-0 at home in La Liga on Sunday to provisionally move five points ahead of nearest challengers Barcelona despite coach Zinedine Zidane making a string of changes in defence.
Stuttering Villarreal closed to within a point of the Champions League qualification places when a second-half Cedric Bakambu double secured a 2-1 comeback win at home to Rayo Vallecano in La Liga on Sunday.
Real Madrid coach Zinedine Zidane is under pressure to break up his misfiring attacking trio of Cristiano Ronaldo, Karim Benzema and Gareth Bale when he takes the La Liga leaders to Alaves on Saturday.
Barcelona are in the middle of an injury crisis as they head to Valencia for Saturday's La Liga game looking to keep up with pacemaking pair Atletico Madrid and Real Madrid. Without injured goalkeeper Jasper Cillessen and right back Sergi Roberto for the last two games, Barca will also be missing defenders Jordi Alba and Gerard Pique after both were hurt in Wednesday's 4-0 win over Manchester City in the Champions League. Pique sprained his right ankle while Alba injured his left hamstring and both are out until November.
The 28-year-old Argentine has scored seven goals from direct free-kicks in this year's La Liga, the latest in Sunday's 5-0 triumph over Espanyol.
Barcelona midfielder Ivan Rakitic embraced the art of winning ugly after they beat 10-man Real Betis 2-0 to move closer to retaining their La Liga title.
Striker Costa ends second spell at Atletico Madrid.
Real Madrid returned to winning ways after last weekend's drubbing at Atletico but failed to convince and were whistled by their own fans during a drab 2-0 victory at home to Deportivo La Coruna on Saturday.
News of all that's transpired on and off the football field
Lajja Gauswami on Tuesday clinched the silver medal in women's 50-metre Rifle 3 Position event, finally bringing to an end India's lean run at the ISSF World Cup in Granada, Spain.
He joins pistol shooter Jitu Rai, rifle shooters Apurvi Chandela and Gagan Narang, who all had sealed berths earlier.
Jitu Rai became the first Indian shooter to qualify for the 2016 Rio Olympics after bagging a quota place with an impressive silver medal-finish at the 51st Shooting World Championships, in Granada.
Lionel Messi scored within three minutes of returning to action for the first time in more than three weeks to help fire La Liga champions Barcelona to a resounding 4-0 home win over Deportivo La Coruna on Saturday.
A bullet header from Nicolas Otamendi put Valencia on course for a 3-1 victory over Eibar in La Liga on Sunday that boosted their hopes of claiming a Champions League place.
Valencia's Paco Alcacer and Dani Parejo both hit doubles in a surprise 5-1 away thrashing of high-flying Celta Vigo in La Liga on Saturday.
James Rodriguez will return to Real Madrid's starting lineup for Sunday's La Liga game at home to Granada after being out for two months with a broken bone in his foot, coach Carlo Ancelotti said on Saturday.
Real Madrid moved to within a point of La Liga leaders Barcelona after Karim Benzema, Isco, Gareth Bale, James Rodriguez and Cristiano Ronaldo all scored in a 5-1 thrashing at struggling Getafe on Saturday.