It wasn't his players' performance but a luck not going his way -- not once but twice -- that saw the Spaniard lose his cool.
'Sanchez is probably back first time on the pitch so that gives this team another boost'
The reigning champions have won 53 and drawn 11 of those 64 games, scoring 169 goals and conceding 42 for a total of 170 points.
Liverpool survived a first-half scare to reach the Champions League final with a 3-2 win at Villarreal on Tuesday that secured a 5-2 aggregate victory after the night had threatened to turn sour for Juergen Klopp's side.
Regardless of whether they eventually win it at home or away, the celebrations that marked their Anfield victory over Queens Park Rangers that won the league in 1990 will not be repeated.
IMAGES from the English Premier League matches played on Wednesday.
A round-up of Tuesday's action in the UEFA Champions League.
'Why should people think I'm not happy here? Because we lost at Anfield or I've lost three games this season? That's an odd reason to say I'm not happy or satisfied to be here'
On a seismic day in the history of Chelsea, Romelu Lukaku scored the winning goal in a 3-2 FA Cup fifth-round victory
Liverpool has displayed a good performance so far in both Premier League and Champions League this season.
Roberto Firmino's 90th-minute header sent Liverpool back to the top of the Premier League with a 2-1 victory over Tottenham Hotspur, whose 11-match unbeaten run came to an end on Wednesday.
Rewind five years and Liverpool hosted Chelsea with three games remaining, knowing victory would have left them six points clear and a first league title since 1990 almost secure.
A round-up of Tuesday's action in the UEFA Champions League.
A round-up of Wednesday's action in the UEFA Champions League.
City were due to open their season against Aston Villa and United against Burnley but those games will be moved.
Images from Sunday's action in the Premier League.
Juergen Klopp's side, chasing their maiden title in the Premier League era and first in the top flight in 30 years, took a 14th-minute lead from a Virgil van Dijk header but had to wait until stoppage time to put the game to bed through Mohamed Salah.
'They were better than us for some spells and we know what awaits us over there' Valverde pointed to his team's sensational exit from last year's competition to AS Roma after a 4-1 cushion from the first leg and said they would be taking nothing for granted in Tuesday's return game at Anfield.
Liverpool analysts had watched how Barcelona players were always distracted when decisions went against them and word was passed down to Carl Lancaster, a coaching mentor at the club's academy, who asked the ball boys to serve their players quickly.
A round-up of Tuesday's action in the UEFA Champions League.
IMAGES from the English Premier League matches played on Saturday.
first English title for 30 years had been sealed almost a month ago with seven games remaining, following a three-month stoppage because of the COVID-19 pandemic.
Images from EPL matches played on Wednesday
Roberto Firmino struck a stoppage-time winner as Liverpool beat Paris St Germain 3-2 at Anfield on Tuesday after Kylian Mbappe looked to have secured a point for the French side in a compelling Champions League Group C clash.
The return leg will be played at Ajax's Johan Cruyff Arena on May 8.
Images from Sunday's English Premier League matches.
IMAGES from the English Premier League matches played on Saturday
In a thriller at Anfield, a weakened Liverpool side came back from the brink to beat Leicester City on penalties after a 3-3 draw, setting up a semi-final against Arsenal.
Liverpool's Robertson frustrated by Neymar 'playacting'
European champions Liverpool are second in their Champions League group - a point behind Napoli - and Klopp's side host Genk at Anfield.
Arsenal squeezed past Liverpool 5-4 on penalties to advance to the League Cup quarter-finals on Thursday after a goalless 90 minutes.
A round-up of Sunday night's matches in the Premier League.
'Soul might not win trophies. But, unlike trophies, soul actually matters,' says Shougat Dasgupta.
Liverpool, who are fifth in the table and have won just one league game since the turn of the year, host fourth-placed Arsenal on Saturday looking to bounce back immediately from one of their worst performances of the season.
Jota's header earned the three points but it was a struggle in the rain for Juergen Klopp's side who looked uneasy at the back without the injured Virgil van Dijk.
Manchester City came from behind twice to earn a 2-2 draw with Liverpool in a breathless and pulsating Premier League encounter, at Anfield, on Sunday. All four goals came in the second half.
As Manchester City fans left Goodison Park after a 2-0 victory over Everton on Wednesday that sent their team back to the top of the Premier League, they aimed their chants across adjacent Stanley Park to title rivals Liverpool.
Liverpool held their nerve to win an astonishing penalty shoot-out 11-10 and edge out Chelsea in the English League Cup final on Sunday after a rip-roaring contest had somehow ended 0-0 after extra time at Wembley.
The win allowed second-placed Liverpool to close the gap on league leaders Manchester City to two points.
The first leg, originally scheduled to be held at the Red Bull Arena in Germany, was shifted to Budapest after German authorities denied Liverpool entry into the country due to COVID-19 protocols.