Barcelona outclassed Mallorca 3-0 at home on Saturday to increase their lead at the top of the LaLiga standings.
The winners of the tie will face Real Sociedad or Athletic Bilbao in the final. Real Sociedad hold a 1-0 advantage ahead of their second leg in San Sebastian on March 4.
Barcelona returned to the top of the LaLiga table with a comfortable 4-0 home victory over 10-man Real Sociedad on Sunday.
Spain face Ronald Koeman's Netherlands away on Thursday before returning home for the second-leg on March 23.
Barcelona captain Raphinha scored twice as they returned to winning ways in LaLiga for the first time in a month with a 5-1 victory at Mallorca on Tuesday.
Barcelona thrashed Real Betis 5-1 on Wednesday to book their spot in the Copa del Rey quarter-finals.
A late penalty from Bryan Zaragoza secured Spain a 3-2 win over Switzerland in their final Nations League Group A4 game on Monday.
Leverkusen's Schick scores hat-trick in comeback win over Heidenheim.
Barcelona top the LaLiga standings with 15 points, four ahead of Real Madrid and Villarreal. Girona are seventh on seven points.
Barcelona made a disappointing start to their Champions League campaign by losing 2-1 to AS Monaco on Thursday.
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