Barca, with Lionel Messi absent through injury, hit the woodwork on four occasions but luck was not on their side as they lost their second consecutive away game following their 4-1 defeat by Celta Vigo.
The 30-year-old was excluded from Spain's squad for this year's World Cup but is hopeful of turning his fortunes around under former Barcelona boss Enrique.
'I feel as confident and motivated as at the beginning. I can't control rumours, but I still have faith'
'I want the market to damn well close so that I know who I can count on'
Valverde's knowledge of Barca and his many years of experience of coaching in Spain saw him pip Argentine Jorge Sampaoli and Luis Enrique's assistant Juan Carlos Unzue to the top job.
The VAR system took several minutes to confirm the ball had not gone out before Mitoma's touch
Barcelona have had to overcome many changes to win their 23rd La Liga title, coach Luis Enrique said.
Angry Barcelona coach Luis Enrique blamed stupid mistakes after the La Liga pacesetters threw away a two goal lead to draw 2-2 at home to Deportivo La Coruna on Saturday. Barca have drawn their last two games in La Liga and could see Atletico Madrid draw level with them if they beat Athletic Bilbao on Sunday, ahead of their trip to the Club World Cup in Japan next week.
Barcelona's amazing 6-1 victory over Paris St Germain on Wednesday that sent them through to the Champions League quarter-finals will forever stay in the memories of supporters, coach Luis Enrique said.
Spain's footballing giants, FC Barcelona won their 23rd La Liga crown after defeating Atletico Madrid 1-0 on Sunday. And after winning, what was their fifth title in seven years, the Barca players let their hair down and celebrated in style at the Vincent Calderon stadium. Rediff.com invites you a peek into their wild celebrations. Have a look...
IMAGES from the Champions League matches played on Tuesday.
Yet even though the Swiss lack world stars like France's Antoine Griezmann, Karim Benzema or Kylian Mbappe, Spain must be prepared for a long evening finding their way through Vladimir Petkovic's disciplined side on Friday in St Petersburg.
'Those of us who are older, who went through difficult times in Brazil and Russia, help the younger ones, with new energy.'
Barcelona coach Luis Enrique expects Lionel Messi to bounce back from a difficult summer with his usual enthusiasm -- and does not rule out a return to international football.
Images from Saturday's Nations League group matches.
Barcelona coach Luis Enrique said on Friday he trusted his team to handle the occasion of this weekend's season finale at lowly Granada, where a win would guarantee their 24th La Liga title.
Barcelona manager Luis Enrique believes his team deserves to win "the best league in Europe" as they aim to clinch La Liga in a potentially thrilling climax to the Spanish season on Saturday.
Praise comes in from all quarters as Argentine breaks Raul's Champions League record.
Spain cannot repeat mistakes from Japan collapse, says Rodri
'They aren't machines, they are the best players in their position but they aren't unbeatable or unsurpassable.'
Barcelona's inconsistency over the season had cost them the La Liga title, coach Luis Enrique has said.
Alves joined Barcelona from Sevilla in 2008 and made 391 appearances, becoming a regular under ex-managers Pep Guardiola, Tito Vilanova, Tata Martino and Luis Enrique before leaving for Juventus in 2016.
As Barcelona prepare to welcome back Pep Guardiola to the Nou Camp for Wednesday's Champions League game against Manchester City, check out how the club has evolved since the visionary coach departed in 2012.
A round-up of Wednesday's action in the UEFA Champions League
Japan's high-pressing style which undid Germany had briefly unsettled Spain on a few occasions in the first half.
Barcelona coach Luis Enrique made no excuses after they lost 4-3 at Celta Vigo and missed the chance to top La Liga on Sunday.
Cameroonian teenager Wilfrid Kaptoum scored a late equaliser to give Barcelona a 1-1 draw at Valencia that wrapped up an 8-1 aggregate success in their King's Cup semi-final on Wednesday.
Lionel Messi's late penalty saw bedraggled Barcelona scrape a 2-1 victory over Leganes on Sunday at a divided Nou Camp as the La Liga champions looked as if they had still not recovered from their harrowing midweek defeat to Paris St Germain.
News of all that's transpired on and off the football field
Rediff.com gives you a glimpse of the jubilant Catalan team...
Barcelona coach Luis Enrique is still not satisfied despite winning five trophies in 2015 and is aiming to do even better next year.
Roundup of Champions League matches played on Wednesday night
Treble-chasing Barcelona are exactly where they want to be as they prepare for two matches this week that could make or break coach Luis Enrique's first season in charge.
Barcelona could be without captain Andres Iniesta for the rest of the year after the midfielder sustained a knee injury in an eventful 3-2 La Liga win for the leaders at Valencia on Saturday.
Luis Suarez, whose four-month ban for biting an opponent expires on Friday, will make his official Barcelona debut in Saturday's La Liga clasico at Real Madrid, coach Luis Enrique said.
Former Barcelona great Michael Laudrup lambasted the Brazil international for "provoking" the opposition in Saturday's 5-1 win at Leganes and Neymar's flamboyant style will be scrutinised again on Wednesday when Barcelona host Atletico.
The enduring image of Luis Enrique for many soccer fans is the Spain player with blood gushing from his nose after a vicious elbow from Italy defender Mauro Tassotti during the 1994 World Cup quarter-final in Boston.
IMAGES from the football matches played across Europe on Sunday.
Barcelona coach Luis Enrique is ready for surprises when he comes up against Pep Guardiola's Bayern Munich on Wednesday in what he believes will be an open and attractive game.