European Champions Spain produced a dominant display to thrash South Korea 6-1 in Salzburg, Austria on Wednesday in their penultimate friendly before Euro 2016.
The Spaniard replaced Luigi Del Neri, daily sports newspaper O Jogo reported.
Atletico Madrid demonstrated their remarkable team spirit to come roaring back from two goals and a man down to draw 2-2 at Liga debutants Girona on Saturday, after Antoine Griezmann had been sent off for the first time in his career.
Unzue is one of the two leading candidates to succeed Luis Enrique, who announced this month he will leave at the end of this season, along with Athletic Bilbao coach Ernesto Valverde.
A superb strike from Jose Luis Morales condemned Real Madrid to a 1-0 defeat away to Levante on Saturday which saw them unseated at the top of the La Liga standings by Barcelona. Real's problems deepened with a suspected ankle injury to Eden Hazard, who limped off the pitch four days before their Champions League showdown with Manchester City and a week before their showdown with Barca in the 'Clasico'. Real's problems deepened with a suspected ankle injury to Eden Hazard, who limped off the pitch four days before their Champions League showdown with Manchester City and a week before their showdown with Barca in the 'Clasico'.
Striker Aduriz opened the scoring in the sixth minute at the San Mames with a trademark header before midfielder Garcia, who joined from Atletico Madrid last month, nodded in a second in the 24th minute.
A round-up of weekend action in the major European leagues.
The two clubs will meet for the fourth time in five seasons in the first knockout phase of the Champions League
Real Madrid have exonerated Argentina winger Angel Di Maria over an incident in Monday's La Liga game at home to Celta Vigo when he was caught on camera grabbing his crotch while being substituted.
Valencia climbed above Atletico Madrid and Sevilla into third in La Liga when Alvaro Negredo came off the bench to score a late winner in a 3-2 home victory over his former club Almeria on Saturday.
After being named this year's UEFA's Best Player in Europe, Portugal and Real Madrid star striker Cristiano Ronaldo has insisted that Atletico Madrid forward Antoine Griezmann deserved the coveted trophy more than him.
However, Arsenal will be without Gilberto and Ashley Cole for the Champions League match against Celta Vigo.
Ajax Amsterdam produced a performance worthy of the club's illustrious past when they crushed Olympique Lyonnais 4-1 on Wednesday to move to the brink of their first European final since 1996.
Zidane plays down Ronaldo injury; Liverpool's Gomez sidelined after surgey
'Rivaldo remains at Milan and tomorrow will leave with the squad for Vigo,' Milan vice-president Adriano Galliani said.
Real Madrid beat Leganes 2-1 in La Liga on Saturday after coach Zinedine Zidane heavily rotated his side in preparation for Tuesday's Champions League semi-final second leg against Bayern Munich, including leaving out top-scorer Cristiano Ronaldo.
Cristiano Ronaldo continued his prolific start to the season with four goals, including two penalties, as Real Madrid came from behind to beat Elche 5-1 in La Liga on Tuesday.
IMAGES from the soccer matches played in Spain and Italy on Saturday
Real Madrid closed to within two points of La Liga leaders Barcelona after demolishing nine-man Rayo Vallecano 10-2 while Atletico Madrid missed a chance to seize top spot outright by losing 1-0 at Malaga.
The Brazilian striker scored twice in a 3-2 victory over Celta Vigo in the Champions League first leg knockout tie.
The Arsenal captain is a doubt for the match against Celta Vigo after injuring his knee on Saturday.
Barcelona lost 1-0 at home to Real Zaragoza on a night of upsets in King's Cup quarter-final, first-leg ties on Thursday.
Barcelona first struggled to come to terms with their shock 4-0 defeat to Paris St Germain in the Champions League last 16 first leg but have sparkled in their last two games and are daring to believe they can defy history by reaching the quarter-finals.
The Spanish League leaders slipped to a 2-0 defeat at home to Real Mallorca.
News of all that's transpired on and off the football field
Cristiano Ronaldo finally became the highest scorer in Real Madrid's history while Bayern Munich set a record for the greatest number of successive wins at the start of a season in the Bundesliga this weekend.
Real went top with one game to play after thrashing Atletico Madrid 4-0 while rivals Sociedad slipped to a 3-2 defeat at Celta Vigo.
Manchester United's hopes of a top four finish suffered a blow on Sunday as relegation-threatened Swansea City came back for a 1-1 draw at Old Trafford.
IMAGES from the La Liga matches played on Sunday
News of all that transpired on and off the football field.
'Barca are the best team around and when we play as we know how we are unstoppable'
Real Madrid tightened their grip on top spot by beating Alaves 3-0 at home in La Liga on Sunday to provisionally move five points ahead of nearest challengers Barcelona despite coach Zinedine Zidane making a string of changes in defence.
Real fought back after a calamitous own goal from keeper Keylor Navas gave Betis the lead in the 25th minute, just after the Costa Rican escaped a possible red card. Cristiano Ronaldo pulled the hosts level in the 41st with a diving header.
Cristiano Ronaldo's new five-year contract with Real Madrid which ties him to the Spanish club until the age of 36 will not be his last, he said on Monday. The 31-year-old forward joined Real in 2009 and is the European champions' all-time leading scorer with 371 goals in 360 games. "The numbers are impressive. I certainly never expected to make history at the best club in the world," the Portugal captain told a news conference. "This new contract is a dream come true. But this is my penultimate contract.
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