While their nearest chasers lost, Olympique Lyonnais succumbing 2-1 at home to struggling Lille and Monaco falling 1-0 at Nantes after a last-gasp Lucas Lima thunderbolt, PSG marched on without ever hitting top gear.
The season-openers for champions Paris St Germain and Olympique Lyonnais were postponed after both teams reached the Champions League semi-finals.
Paris St Germain's league record 36-game unbeaten streak came to an abrupt halt when they lost 2-1 at Olympique Lyonnais on Sunday.
News of all that's transpired on and off the football field
Kane began the night level on 19 goals with Liverpool's Mohamed Salah in the race for the Golden Boot.
News of all that transpired on and off the football field.
Images from soccer matches played across different leagues in Europe on Sunday
The 21-year-old Denmark international has made 22 appearances for the English champions this term having cemented his place at the heart of Antonio Conte's three-man defence.
The draw interrupted a run of four straight league wins for Zinedine Zidane's side and left them second on 67 points after 31 games, three behind leaders Atletico who thrashed Eibar 5-0 earlier in the day.
Ligue 1 leaders Olympique Lyonnais were knocked out of the French Cup 3-2 at Nantes on Tuesday with Vincent Bessat grabbing a hat-trick in the last-32 game on a night of upsets.
Images from Sunday's action in La Liga and Ligue 1.
Lionel Messi scored his 650th goal for Barcelona while Antoine Griezmann struck the winner in a 2-1 home success over Athletic Bilbao
Chelsea's struggle to retain the title is hardly surprising as the club returned to the Champions League and their league rivals strengthened their squads, former Leicester City manager Claudio Ranieri has said.
Manchester United will swoop for Sweden striker Zlatan Ibrahimovic on a free transfer as new manager Jose Mourinho's first marquee signing at Old Trafford, Sky Sports has reported.
The winning photos of this year's Nikon annual Small World Photomicrography Competition.
News of all that's transpired on and off the football field
News of all that's transpired on and off the football field
Atletico Madrid took a giant step towards the La Liga title
Werder Bremen's on-loan Chelsea defender Papy Djilobodji has received a three-match ban for making a throat-slitting gesture in Saturday's 1-1 Bundesliga draw with Mainz.
Atletico Madrid have signed striker Luis Suarez from Barcelona, the Spanish clubs said on Wednesday, bringing to an end his six-year stint at the Camp Nou.
News of all that's transpired on and off the football field.
Zlatan Ibrahimovic celebrated his last game at the Parc des Princes with Paris St Germain by breaking the club's goal record in a top flight season in the French champions' 4-0 win against Nantes in the final round of Ligue 1 on Saturday.
France coach Jacques Santini's team for the FIFA centenary match against Brazil in Paris on May 20.
Images from Sunday's action in La Liga, Serie A and Ligue 1.
News of all that's transpired on and off the football field
News of all that's transpired on and off the football field
Images from football matches played across Europe.
An ankle injury will keep the veteran goalkeeper out of the matches against Israel and the Faroe Islands.
Lionel Messi was at the top of his game as Barcelona earned a 3-2 win at Athletic Bilbao on Wednesday to move up to third in La Liga.
Lilian Laslandes struck twice to help in-form Girodins Bordeaux beat Nantes 3-1 and reach the quarter-finals of the French League Cup.
Unai Emery's Villarreal were much improved in the second half and had spurned numerous chances before Moreno's leveller.
The blast took place at a packed gymnasium in Parang town in southern Philippine
News of all that's transpired on and off the football field
Manchester United took over at the top of the Premier League while Barcelona's Argentine forward Lionel Messi could be out for up to two months with a knee injury and rampant Bayern Munich extended their perfect start to seven league wins.
News of all that's transpired on and off the football field
Real Madrid lifted the FIFA Club World Cup for a record fourth time on Saturday after thrashing local side Al Ain 4-1 in the final in Abu Dhabi with the help of impressive distance strikes in either half from midfielders Luka Modric and Marcos Llorente.
News of all that's transpired on and off the football field
News of all that's transpired on and off the football field
Mbappe struck in the 74th minute to put PSG on 80 points from 29 games and on the brink of retaining the title with second-placed Lille, who beat Nantes 3-2 away earlier on Sunday, still 20 points behind having played a game more.