The reigning Ballon d'or winner gave a perfect start to his side's new campaign by scoring twice in Madrid's comfortable 3-0 win over Cypriot visitors APOEL in the opening match.
Real Madrid tore apart Bayern Munich's ragged defence with a ruthless first-half display as they thrashed the defending champions 4-0 in their own stadium to reach their first Champions League final for 12 years.
Real Madrid overcame an early howler from Sergio Ramos to beat Real Sociedad 3-1 at home on an eventful Saturday at the Santiago Bernabeu, where Gareth Bale was loudly booed by his own supporters and Luka Modric returned to his very best form.
Spain coach Luis Enrique promised evolution rather than revolution when he took charge of the national side following their disastrous World Cup campaign this year when they were eliminated in the round of 16.
Karim Benzema gave the European champions the lead in the 20th minute with an irresistible piece of control and finish after a pinpoint pass from Luka Modric.
Liverpool defender Martin Skrtel was charged with violent conduct for appearing to stamp on Manchester United goalkeeper David De Gea.
Spain snatched a 2-2 draw against Morocco on Monday to qualify for the World Cup last 16 and take top spot in Group B ahead of Portugal on goals scored.
Cristiano Ronaldo was booed by Real Madrid fans despite grabbing one goal and laying on another in their 2-0 Champions League last-16 second leg win over AS Roma on Tuesday.
Manchester City marched into the quarter-finals of the Champions League
The win took second-placed Real to 62 points after 29 games, two behind champions Barca who beat Leganes 2-0 on Tuesday.
Cristiano Ronaldo scored twice as Real Madrid came from behind to beat Paris St Germain 3-1, while Sadio Mane grabbed a hat-trick as Liverpool demolished Porto 5-0 away in the Champions League round-of-16 on Wednesday.
"We are not going to deviate one iota from our footballing concepts," the distinguished former Spain defender Hierro said.
The victory saw Spain finish top of League A4 with 11 points after six games, joining France in the final four tournament, which will take place in October 2021.
Spain forward Ansu Fati became the national team's youngest ever goalscorer as the 17-year-old inspired Luis Enrique's side to a resounding 4-0 win at home to Ukraine in the UEFA Nations League on Sunday.
Real Madrid's Javier Hernandez struck twice as they came from behind to beat Celta Vigo 4-2 away and keep the pressure on Barcelona at the top of La Liga on Sunday.
Real Madrid ended their long wait for a La Liga victory by beating Real Valladolid 2-0 on Saturday with two late goals in interim coach Santiago Solari's first home game in charge of the struggling European champions.
Cristiano Ronaldo's agent has defended the FIFA Ballon d'Or winner after he was criticised for throwing a lavish 30th birthday party on Saturday hours after Real Madrid's 4-0 La Liga drubbing at Atletico.
The Frenchman, who won nine trophies in two-and-a-half years, suggested it is events off the pitch, rather than on it, that made him leave.
The result continued a dismal streak for Madrid, who have won only two of their last five games in all competitions
Real Madrid forwards Marco Asensio and Karim Benzema struck to give their side a 2-0 win at home to Eibar in La Liga
Gareth Bale scored his 25th goal for Wales but Georgia fought back strongly to earn a deserved 1-1 draw in a World Cup Group D qualifier in Cardiff on Sunday. It left Wales, surprise semi-finalists at Euro 2016, with five points from three games and at risk of losing the group leadership after the day's later matches. Georgia took their first point, following narrow defeats by Austria and Ireland.
A summary of Saturday's action in Serie A and La Liga.
Pepe opened the scoring for Real with a looping header that flew past Jan Oblak in the 52nd minute and it looked like the hosts would earn three points to move five clear of Barcelona at the top of La Liga.
Barca finished the season second in the standings on 82 points, four behind champions Real Madrid who visit Leganes later on Sunday. Alaves are 16th on 39.
Real Madrid clinched a record-extending 34th La Liga title with one game to spare by beating Villarreal 2-1 at home on Thursday thanks to two goals from their leading scorer Karim Benzema. Real have 86 points after 37 games, seven more than deposed champions Barcelona who were beaten 2-1 at home to Osasuna.
Barcelona forward Luis Suarez scored a hat-trick as his side thrashed arch-rivals Real Madrid 5-1 on Sunday in a highly entertaining 'Clasico' which surely will signal the end of hapless coach Julen Lopetegui's spell in charge of Real.
Two years on from their defeat by Real Madrid in the Champions League final, Atletico Madrid are back on the same stage against the same rival - wiser and determined not to be haunted by the memories of Lisbon.
Real Madrid goalkeeper Iker Casillas was forced off in the 15th minute of Tuesday's 6-1 Champions League Group B romp at Galatasaray after sustaining a rib injury in a collision with team mate Sergio Ramos.
News of all that's transpired on and off the football field
Zidane calls on Madrid fans to create best atmosphere ever against Bayern
The result shook up League A Group 4, giving Ukraine an outside chance of finishing top of the group with two games remaining.
Portugal and Real Madrid forward Cristiano Ronaldo was named the world's best footballer for the second time on Monday, preventing his great rival Lionel Messi from winning the award for a fifth year in a row.
Real Madrid moved into the semi-finals of the Champions League after their makeshift defence held on for 0-0 second-leg draw with Liverpool at Anfield on Wednesday to complete a 3-1 aggregate win.
Pepe has blasted the Liga club's fans as "unenthusiastic", contrasting the hushed atmosphere of the Santiago Bernabeu stadium with the cauldron of noise he is now exposed to with Turkish champions Besiktas.
Real Madrid coach Zinedine Zidane is happy with his squad and the club has not discussed possible reinforcements despite FIFA's decision to ban them from the next two transfer windows, he said on Saturday. FIFA announced on Thursday it had banned Real and neighbours Atletico Madrid from registering players for the next two windows for breaching rules on signing non-Spanish Under-18 players. Both clubs denied wrongdoing and said they would appeal. The list of players included at least one of Zidane's four sons, who play for various Real youth teams, although the club have not confirmed which of them were singled out by FIFA.
'I'm not asking them to name streets after me, the only thing I ask is that they don't boo me here'
The Real Madrid forward apologises after Real Madrid dumped out of King's Cup by Atletico Madrid.
Real Madrid winger Gareth Bale answered his critics in emphatic style.
Real Madrid's Spanish record 22-match winning streak ended in a 2-1 La Liga defeat at Valencia on Sunday with Nicolas Otamendi heading in the second-half winner.