Athletic Bilbao missed a chance to tighten their grip on Spain's fourth Champions League qualification place when they had to come from behind to rescue a 1-1 draw at 10-man Villarreal in La Liga on Monday.
The Bavarians have now won the German league title a record 29 times.
Centre-back Eric Abidal and midfielder Samir Nasri were missing when France coach Didier Deschamps named a 24-man squad on Thursday for next week's friendly against the Netherlands.
Barcelona have been boosted by the successful return from injury of talismanic playmaker Andres Iniesta as they prepare to host city rivals Espanyol in La Liga on Sunday.
The Belgian forward came off the bench to make his Real debut in Saturday's 3-2 win over Levante, having had his start to life at the club hit by a thigh injury the day before the La Liga season began.
Real Madrid's Sergio Ramos scored in the 90th minute to hold FC Barcelona to a 1-1 draw at the Camp Nou on Saturday.
Cristian Tello hit a hat-trick as Barcelona came from behind to win 4-1 in their King's Cup quarter-final first leg at Levante on Wednesday and Lionel Messi celebrated his 400th appearance for the Catalan side.
Brighton and Hove Albion scored late to earn a 1-1 draw at Crystal Palace. Sheffield United and Fulham also drew 1-1 as both teams picked up their first points.
Belgium have retained injured Vincent Kompany in their final World Cup squad but put fellow defender Laurent Ciman on standby in case the Manchester City skipper is not fit for their opening match in Russia.
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Following a bright start to the season it was another disappointing display by Villarreal, who have one win from seven games in La Liga, before the return at El Madrigal in two weeks.
Real Madrid captain and goalkeeper Iker Casillas has called for a big improvement after the European champions suffered a surprise early-season setback at Real Sociedad in La Liga on Sunday.
Joao Miranda and new signing Mario Mandzukic led Atletico Madrid to a 2-1 home win in La Liga on Saturday as visitors Eibar were unable to cope with the aerial threat of the champions.
Treble-chasing Barcelona are exactly where they want to be as they prepare for two matches this week that could make or break coach Luis Enrique's first season in charge.
Karim Benzema scored twice after the interval with a penalty and a header from a corner to give Santiago Solari's side a 3-1 lead, after Raphael Varane struck in the 34th minute to cancel out Anuar Tuhami's goal for Valladolid five minutes earlier.
Barcelona came through a testing local derby at Espanyol, winning 3-0 to cling to their slender lead at the top of La Liga after rivals Real Madrid had set the challenge by beating Valencia 2-1 in the earlier kick-off.
Antoine Griezmann headed two goals for Atletico Madrid in a 3-1 victory over Levante that kept them on the heels of La Liga leaders Real Madrid on Saturday.
Real Madrid dropped points for the third time in seven games since Zinedine Zidane's return as they were held to a 0-0 draw away to Getafe in La Liga on Thursday, which harmed their neighbours' hopes of a top-four finish.
Arsenal led a list of nine clubs who grabbed a second win in as many games in the Europa League group phase as France striker Olivier Giroud scored his 100th goal for the club in a 4-2 win at BATE Borisov on Thursday.
Villarreal landed a stunning blow on a potential rival for a European qualification berth when Giovani dos Santos and Ikechukwu Uche each struck twice in a 5-1 drubbing of Real Sociedad in La Liga on Monday.
Holders Barcelona crashed out of the Champions League after being stifled by a brilliantly well-organised Atletico Madrid.
Seven-times champions AC Milan, knocked out of the Champions League by Barcelona in the last two seasons, were drawn against the Catalans again in the group stage of this season's competition on Friday.
Neymar's double helped Barcelona cruise to a 5-0 victory in the first leg of their King's Cup last 16 tie against Elche.
A round of Saturday's matches in Series A, La Liga and Bundesliga.
With the distraction of two individual scoring records safely out of the way, Barcelona forward Lionel Messi can turn his full focus on helping the club win the major silverware that eluded them last season.
A late goal by Toni Kroos sealed victory as Real Madrid defeated an impressive Celta Vigo side 2-1 to win their first home La Liga game of the campaign on Saturday.
Barcelona made a brisk start to the season with new coach Luis Enrique at the helm in place of Gerardo Martino and a host of additions to the squad, including midfielder Ivan Rakitic and goalkeeper Claudio Bravo.
Cristiano Ronaldo took his tally for the La Liga season to a phenomenal 13 goals in six appearances with his third treble of the campaign as Real Madrid romped to a 5-0 win at home to Athletic Bilbao on Sunday.
Champions Barcelona suffered their second defeat in three matches in La Liga on Saturday, with Michael Krohn-Dehli scoring and setting up another goal in a 2-1 victory for Sevilla.
Underlying tensions mean Luis Enrique will not be remembered with the same reverence as Pep Guardiola, even though he has delivered a similar trophy haul.
Cristiano Ronaldo admits that he suffered for pushing himself too much at the end of last season but is now close to his best as Real Madrid prepare to face Real Sociedad this weekend.
Messi stretched Barca's lead by finishing off a brilliant move with Luis Suarez in the 50th minute and the Uruguayan joined his close friend and strike partner on 15 league goals by robbing an Eibar defender and finishing inside the near post in the 68th.
Red Star, who won the European Cup in 1991 and reached the latter stages the following season, finished second in Group H behind Arsenal who crushed BATE Borisov 6-0.
Carlos Vela helped Real Sociedad overcome a European hangover when he grabbed a second-half equaliser to earn a 1-1 draw at promoted Elche in La Liga on Saturday.
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Real Madrid captain Sergio Ramos again came to his side's rescue as they snatched a dramatic 3-2 victory over Deportivo La Coruna on Saturday to keep Zinedine Zidane's side six points clear at the top of La Liga and set a club record 35 games unbeaten.
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Barcelona's Lionel Messi, Luis Suarez and Neymar motored past 100 goals for the season.
Barcelona dropped their first points of the La Liga season as their star-studded forward line misfired in a 0-0 draw away to Malaga on Wednesday.
Real Madrid set up a King's Cup semi-final against holders Atletico Madrid or Athletic Bilbao when they beat Espanyol 1-0 in their quarter-final, second leg on Tuesday for a 2-0 aggregate success.