Michael Owen scored the winning goal five minutes from time to give Liverpool a 2-1 victory in the Champions World Series.
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AC Milan won their 17th Italian title as they lifted the Serie A crown for the first time since 1999 with a 1-0 win over second-placed AS Roma.
Napoli striker Gonzalo Higuain and evergreen AS Roma forward Francesco Totti lit up Serie A on Monday as the two teams won in contrasting fashion to boost their bids for an automatic Champions League spot.
Barcelona's last Champions League triumph came in 2015, and since then they have failed to get beyond the quarter-finals while Real Madrid have monopolised the trophy.
Fiorentina tore apart Italian rivals AS Roma to reach the Europa League quarter-finals with a 3-0 win that left their opponents' season in tatters and under-fire coach Rudi Garcia tottering on the brink of the sack.
AS Roma's Italy international forward could leave unless the squad is strengthened by some big-name signings.
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Brazilians Serginho and Rivaldo could make a late bid for places in the starting line-up for the Champions League final against Juventus.
Cristiano Ronaldo finally became the highest scorer in Real Madrid's history while Bayern Munich set a record for the greatest number of successive wins at the start of a season in the Bundesliga this weekend.
The result left Milan in third place in the Serie A league.
The day after AC Milan and Juventus drew 1-1, AS Roma president Franco Sensi said the result was planned.
The Chelsea coach insisted that his thoughts remained focused entirely on Tuesday's match agaimst Lazio.\n\n
Images from the Europa League matches played on Thursday
European champions AC Milan beat Lazio 1-0 at the San Siro on Sunday to join Juventus at the top of Serie A.
Italy's top-flight Serie A soccer league launched a new anti-racism campaign on Monday by presenting artwork featuring three side-by-side paintings of apes but the move has been described by campaign group Fare as a sick joke. News of all that's transpired on and off the football field.
There is never a dearth of drama in European football and here is proof...
News of all that's transpired on and off the football field
The victory saw the unfashionable Madrid club tighten their grip on the coveted fourth spot in the table by moving on to 58 points after 36 games, three points clear of nearest challengers Sevilla, who lost to Leganes on Friday.
Juventus launched their bid for a sixth successive league title after their record signing Gonzalo Higuain came off the bench to grab a trademark winner in a 2-1 success over Fiorentina on the opening day of the Serie A season.
IMAGES from the soccer matches played in Spain and Italy on Saturday
Leonardo Bonucci and Alvaro Morata were on target as Juventus defeated Inter Milan 2-0 in the 'derby of Italy' to open a four-point lead at the top of Serie A on Sunday.
He made it 3-0 with a superb first-time finish into the bottom corner in the 20th minute, scoring his first ever treble in a competitive game, more than 19 years after making his professional debut.
Juventus coach Massimiliano Allegri complained about his team's finishing after the Serie A leaders were held to a goalless draw at Fiorentina.
AC Milan won the Italian Cup with a 2-2 draw with AS Roma in the second leg of the final on Saturday.
Benzema to stand trial in sex tape case, says lawyer.