Bravo stopped Portugal's first three spot kicks from Ricardo Quaresma, Joao Moutinho and Nani while Chile converted their first three to win the clash of South American and European champions.
Brazil and Portugal fought themselves into a stalemate on Friday but the 0-0 draw was enough for both teams to go through comfortably into the second round of the World Cup.
Portugal enjoyed their biggest ever World Cup victory when they overwhelmed North Korea 7-0 in Group G on Monday to end the Asian side's hopes.
Nuno Maniche showed his worth once again scoring the solitary goal for Portugal against the Netherlands on Sunday
Portugal proved they can flourish without their talismanic forward Cristiano Ronaldo, at least on the pitch, in beating France to win Euro 2016. Coach Fernando Santos has been trying to reduce their dependency on Ronaldo and his team's ability to live without their alltime leading scorer and captain faced its ultimate test when he was went off injured after 25 minutes of Sunday's final. They passed with flying colours. Relieved of any obligation to pass to Ronaldo every time he was free or allow him to take free kicks, Portugal's players appeared less inhibited without him on the pitch.
Cristiano Ronaldo has been one of Portugal's biggest culprits, missing an easy chance late in the 1-1 draw with Iceland and firing a penalty against the post late in the Austria match.
Rodri won the Ballon d'Or award for the best player in the world, beating Brazil's Vinicius Jr and England's Jude Bellingham.
Cristiano Ronaldo finally ended his dry spell for Portugal with a quasi-comical goal, but the real drivers behind Portugal's sumptuous 7-0 rout of North Korea on Monday were midfielders Raul Meireles and Tiago.
Besides taking in the beauty of Portugal's capital, Lisbon, Abhijit Masih also took a tour of the nearby towns of Obidos, Batalha, Nazare and Fatima in the course of his travels there. Read his account and learn why they are a must-see if you ever find yourself in that part of the world.
After teetering on the brink of first-round elimination and being involved in the most boring match of the tournament, there is now a real chance Portugal could muddle their way through to the Euro 2016 final. A kind draw has left Portugal with an eminently winnable quarter-final against Poland which would be followed by a semi-final against Wales, Hungary or Belgium.
Euro 2016 finalists Portugal received a boost on Saturday when central defender Pepe trained with his teammates and appeared to be free of any injury problems.
Gomes, who also played in Spain and Morocco, died after a long illness.
The medals tally at the Paris 2024 Paralympics.
IMAGES from the Europa League matches played on Thursday
Portugal's Silvestre Varela scored a dramatic 87th-winner to give his side a 3-2 win over Denmark in a pulsating Euro 2012 Group B match on Wednesday.
Wasteful Portugal were held to a 1-1 home draw by Serbia after their captain and top scorer Cristiano Ronaldo limped off with an apparent hamstring injury in the first half of their Euro 2020 Group B qualifier on Monday.
India has got a breather with the constitutional court of Portugal staying the order of its Supreme Court on violation of extradition agreement of underworld don Abu Salem by New Delhi by slapping new charges invoking death penalty.
England coach Sven-Goran Eriksson sees the match against Portugal as a chance to test his players against one of the most technically accomplished sides in the world.
The hosts became the first team into the semi-finals of Euro 2004, winning 6-5 on penalties after extra-time ended 2-2.
Mario Gomez thumped in a superb 72nd-minute header to give Germany a 1-0 victory over Portugal after they had been frustrated for long periods of a cagey Euro 2012 Group B match on Saturday.
Portugal beat a 10-man Russia 2-0 to keep alive their hopes of making the last eight.
Cristiano Ronaldo led the way as Portugal hit four goals in the last 15 minutes in their World Cup Group Three qualifier.
Portugal captain Luis Figo found it hard to express his feelings after leading the hosts into the Euro 2004 final with a 2-1 victory over the Netherlands on Wednesday.\n\n
Fear of further semi-final failure is all that stands in the way of a classic when slick-passing Portugal meet a fast improving Netherlands side.
The England captain says his team is fully fired up for Thursday's quarter-final.
Matches will be played almost every day according to a new fixture list the league released on Saturday.
While the tournament saw the emergence of young stars, the usual suspects, the big names flattered to deceive.
Portugal coach Luiz Felipe Scolari criticised his team's second-half performance in their 2-0 win over Russia.
Portugal midfielder Maniche and playmaker Deco have been ruled out of the next two World Cup Group One qualifiers in Sweden and Albania.
The All India Football Federation, on Wednesday appointed Portugal's Luis Norton de Matos as the head coach of the India U-17 team for the FIFA U-17 World Cup scheduled to be held in October this year.
'Cristiano Ronaldo v Lionel Messi' got top billing at a packed Old Trafford but it was a lesser light who scored as Portugal scraped a 1-0 friendly win over Argentina on Tuesday.
Manchester United assistant manager Carlos Queiroz has been appointed Portugal coach, the Portuguese Soccer Federation (FPF) said on Friday.
Thomas Mueller scored a hat-trick as Germany beat Portugal 4-0 in an action-packed World Cup Group G match in Salvador, on Monday.
Harnoor Channi-Tiwary decided to visit Spain and Portugal for her first European vacation. This is her travelogue.
The Portugal high court has ordered revocation of the extradition of underworld don Abu Salem accusing Indian probe agencies of violating the conditions under which he was permitted to be taken to India in November 2005 to face trial in eight cases including 1993 Mumbai blasts.
New Zealand's Lisa Carrington completed a stunning clean sweep of gold medals in her Olympic events at by winning the women's kayak single 500 metres title.
'If I'm too nice, it doesn't help in that position.' 'My position almost asks me to be aggressive and not very nice.'
