Carlo Ancelotti's side were then reduced to 10 men in the 79th minute when Vinicius Jr was shown a straight red card for slapping Valencia goalkeeper Stole Dimitrievski.
A round-up of Sunday's Nations League second leg quarter-final matches.
Barcelona joined Real Madrid, Atletico and Real Sociedad in the semi-finals, with the draw set to take place on Wednesday.
Real Madrid's Spanish record 22-match winning streak ended in a 2-1 La Liga defeat at Valencia on Sunday with Nicolas Otamendi heading in the second-half winner.
Robert Lewandowski's brace earned depleted Barcelona a 2-1 comeback win at Valencia
Real Madrid said their participation in the tournament was never in question.
Real Madrid star Vinicius racially attacked for 10th time this season.
The ICC is unlikely to take any action on Pakistan Cricket Board's complaint for alleged boorish crowd behaviour during their World Cup game against India in Ahmedabad on October 14,
Valencia forward Carlos Soler scored a hat-trick of penalties as his side beat La Liga champions Real Madrid 4-1 at home in an extraordinary match on Sunday.
La Liga champions Barcelona fell to their first defeat in three games under new coach Quique Setien as they were beaten 2-0 away at Valencia on Saturday. Barca are still top of the standings on 43 points after 21 games but second-placed Real Madrid, who are also on 43, can go three points clear at the summit if they beat Real Valladolid away from home on Sunday.
Valencia, who lifted the trophy on their last appearance in the showpiece match in 2008, will meet 30-times winners Barca in the final on May 25 at Betis' Benito Villamarin stadium.
The late equaliser saw Valencia left on eighth spot with 27 points in the standings. Here are Images from the exciting draw played at Mestalla in Valencia, on Sunday.
Valencia trailed 2-1 from the away leg and despite a late midweek kick off time supporters still flocked to the Mestalla stadium hoping to see their embattled team turn the tie around.
Barcelona have asked Spain's Court for Sport (TAD) to open disciplinary proceedings against La Liga chief Javier Tebas after he criticised the team's reaction to an empty bottle being thrown in from the stands during a goal celebration.
Atalanta coach Gian Piero Gasperini has sought to clarify comments he made that suggested he had been suffering from novel coronavirus symptoms before and during the Italian team's Champions League last-16 second leg match at Valencia. Gasperini confirmed in the interview that he had since tested positive for COVID-19 from an antibodies test.
Valencia's Paco Alcacer, Dani Parejo and Pablo Piatti found the target as they took full advantage of the first-half dismissal of Malaga's Sergi Darder to win 3-0 at the Mestalla on Friday.
Pierre-Emerick Aubameyang scored his first three goals for Barcelona in a 4-1 win at Valencia, but Inter Milan suffered a shock 2-0 home defeat by Sassuolo. Images from the football matches played on Sunday.
Valencia will banish a fan who hit Barcelona forward Lionel Messi on the head with a plastic bottle on Sunday for life once they have been identified, the club said on Monday.
Cristiano Ronaldo's Champions League debut for Juventus lasted only 29 minutes as he was red-carded but the Italians began their Group H campaign impressively with a 2-0 victory at Valencia on Wednesday. Penalties either side of halftime by Miralem Pjanic sealed the points for the visitors as Valencia's return to European competition after a two-year absence fell flat.
RB Leipzig's Marcel Sabitzer scored two early goals as they eased past last year's Champions League finalists Tottenham Hotspur 3-0 in their last 16 second leg tie on Tuesday to reach their first quarter-finals.
The referee said in his match report he showed the card because Messi "delayed his return to his half of the pitch after the goal was scored with the intention of wasting time".
Sofiane Feghouli's late goal eased the nerves at Valencia's Mestalla as the Spanish club grabbed a 3-1 victory over Monaco in the first leg of their Champions league play-off round tie on Wednesday.
Gareth Bale hailed a "perfect night" after his stunning winner for Real Madrid against Barcelona in Wednesday's King's Cup final, his first trophy since moving to Spain for a record fee in the close season.
On a seismic day in the history of Chelsea, Romelu Lukaku scored the winning goal in a 3-2 FA Cup fifth-round victory
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Gareth Bale raced away to score a stunning late winner as Real Madrid made light of the absence of top scorer Cristiano Ronaldo to beat arch-rivals Barcelona 2-1 to win a riveting King's Cup final on Wednesday.
Kevin Gameiro grabbed a stoppage-time equaliser for Valencia after Denis Cheryshev had reduced the deficit with 20 minutes remaining, leaving the tie in the balance heading into the second leg at the Mestalla stadium on February 28.
The attractive football preached by Swansea City manager Michael Laudrup was displayed to great effect when the Welsh side stunned 10-man Valencia with a 3-0 away victory in the Europa League.
Malaga's outspoken Qatari owner Abdullah Al Thani hit out at the La Liga club's players on Sunday after their hopes of qualifying for the Champions League were dealt a blow in Saturday's 5-1 defeat at Valencia.
Dramatic finale as Valencia denied by 10-man Levante
Columbian pop singer, Shakira was spotted in the crowds during the King's Cup final between Barcelona and Real played at Valencia's Mestalla stadium on Wednesday.
Lionel Messi fired Barcelona into the last 16 of the Champions League with two goals in their 3-0 victory at Spartak Moscow on Tuesday but holders Chelsea are walking a tightrope after a crushing defeat by Juventus.
IMAGES from soccer matches played across Europe on Sunday.
Paris St Germain's 2-1 Champions League win at Valencia on Tuesday is proof that the big-spending Ligue 1 club have become a force in Europe but they should not get carried away, according to director of football Leonardo.
Valencia are expecting a counter-attacking team such as Real Madrid rather than a possession-hungry side like Barcelona when they host Paris St Germain in the Champions League on Tuesday, coach Ernesto Valverde said.
Lionel Messi scored in his 12th consecutive La Liga game to help leaders Barcelona earn a 1-1 draw at Valencia, allowing second-placed Atletico Madrid to close to within nine points after a 1-0 win over Real Betis on Sunday.
Real Madrid put themselves on course for a place in the King's Cup semi-finals after securing a 2-0 first leg victory over Valencia at the Bernabeu on Tuesday.
Injury-hit Barcelona will not be complaining if another 'lucky' black cat helps Lionel Messi find the net at the Nou Camp on Wednesday when they bid for a third King's Cup final appearance in four years.
Injury-hit Barcelona will not be complaining if another 'lucky' black cat helps Lionel Messi find the net at the Nou Camp on Wednesday when they bid for a third King's Cup final appearance in four years.
Lionel Messi had a penalty saved early in the second half as Barcelona were held to a 1-1 draw at Valencia in a hard-fought King's Cup semi-final first leg on Wednesday.