Batsman Fawad Alam, who was also named in the 20-member squad along with two specialist spinners could make a comeback to Pakistan's Test team after 11 years.
Four other players -- Kashif Bhatti, Haris Rauf, Haider Ali and Imran Khan -- tested positive for the second time earlier this week.
The selectors have also put Bilal Asif, Imran Butt, Musa Khan and Mohammad Nawaz on standby to cover for any player who fails pre-tour COVID-19 Testing scheduled later this month.
Azhar was named Test captain this month in place of Sarfaraz Ahmed whose spot as wicketkeeper has been taken by Mohammad Rizwan.
Six of the 10 Pakistan cricketers bound for England who tested positive for COVID-19 have now registered negative results on re-testing, the Pakistan Cricket Board (PCB) said on Saturday. Mohammad Hasnain, Shadab Khan, Fakhar Zaman, Mohammad Rizwan, Mohammad Hafeez and Wahab Riaz, however, must return a second negative result before they can join the main squad of 20 players who will leave for England on Sunday.
'He is a really exciting talent and probably the guy I am looking forward to seeing the most this summer. I have seen the Aussies a lot and I have seen a lot of the Kiwis, but I am really excited to see him'
Pakistan play a three-match Test series against England starting on August 5, followed by three T20 International matches.
'They have got so much talent. And in the last 10 years when they have not been playing home Test matches (for security reasons), they have done a remarkable job to be as competitive as they have and continue to bring on the level of talented players they have.'
Seven more Pakistan players tested positive for COVID-19 throwing into doubt their tour of England starting next month. Kashif Bhatti, Mohammad Hasnain, Fakhar Zaman, Mohammad Rizwan, Mohammad Hafeez, Wahab Riaz and Imran Khan are the players from the England-bound squad who tested positive, the Pakistan Cricket Board announced on Tuesday.
The 34-year-old replaced Iftikhar Ahmed, who managed only 44 runs in four innings in the recent tour of Australia where Pakistan lost both Tests.