Rangers joined Barca in the last eight despite losing 2-1 at Red Star Belgrade, progressing 3-2 on aggregate.
Leverkusen finally subdued Besiktas with two goals in the last 13 minutes to secure the 2-1 win they needed to overhaul their Turkish opponents for third place in Group B.
Tottenham Hotspur, Newcastle United, Blackburn Rovers and Rangers secured four berths for British teams in the knockout phase of the UEFA Cup on Thursday.
Images from Europa League matches played on Thursday.
Bayern remained unruffled by the two-month break due to the novel coronavirus pandemic and beat Dortmund last month to overcome the last major obstacle en route to a 29th Bundesliga title since the introduction of the top division in 1963.
The Brazilian midfielder signed from Serie A rivals AS Roma for 28 million euros.
Bayer Leverkusen stayed in the hunt for a top-four finish in the Budesliga after two goals by striker Kai Havertz as well as one each by Mitchell Weiser and Kerem Demirbay helped them to a 4-1 win at struggling Werder Bremen on Monday. The result left Bayer fifth on 50 points from 26 games, one behind fourth-placed Leipzig and eight adrift of leaders Bayern Munich. Werder, who suffered a record-extending seventh straight home defeat, stayed 17th on 18 points from 25 matches.
Bayer Leverkusen will be without five regulars when they taken Liverpool in the Champions League knock-out tie.
A round-up of weekend action in the main European leagues.
"We are pleased with the win, the many chances and the 70,000-plus spectators."
Germany midfielder Marco Reus scored one goal and set up another in three minutes as Borussia Dortmund survived a late comeback to beat Augsburg 3-2 on Friday and bounce back from an opening Bundesliga defeat last week.
A round-up of Tuesday's action in the UEFA Champions League.
Tottenham Hotspur's France goalkeeper Hugo Lloris has signed a new contract that will take him through to 2022, the Premier League club said on Thursday. The 29-year-old, who captains club and country, has made 189 appearances for Spurs since joining from Olympique Lyonnais in 2012 for a fee of about 12 million pounds ($14.81 million). "I'm very pleased with this new contract," Lloris told the club website
Patrik Schick put the Czechs in front three minutes before half-time as he towered above two defenders to power home a header, but his second goal seven minutes into the second half will almost certainly be one of the tournament's greatest.
Chelsea, Manchester United and Arsenal are all preparing for sudden-death Champions League games.
The Spanish giants drew 1-1 at home to Bayer Leverkusen in the Champions League.
A slip-up could spell the end of their hopes of making the next round in the Champions League.
Bayer Leverkusen rallied with three second-half goals to beat AS Roma 3-1 in a Champions League Group B match on Tuesday.
A round-up of Wednesday's action in the UEFA Champions League.
Manchester United's plane had to abort its landing seconds from touchdown as the squad flew to Germany for Wednesday's Champions League match with Bayer Leverkusen, British media reported.
The 27-year-old East Germany-born midfielder's elegance on the pitch should not be mistaken for arrogance.
Arsenal will face manager Arsene Wenger's former club Monaco with defending champions Real Madrid pitted against German club Schalke.
Hertha Berlin snatched their first Bundesliga victory of 2016 on Friday, edging past Cologne 1-0 thanks to a Vedad Ibisevic goal as the visitors tightened their grip on third place.
Five-time winners Sevilla made light work of AS Roma when first half goals from Sergio Reguilon and Youssef En-Nesyri gave them a 2-0 win over AS Roma and sent them into the Europa League quarter-finals on Thursday.
A round-up of Wednesday's action in the UEFA Champions League.
Bayer Leverkusen beat a second-string Bayern Munich 2-0 on Saturday to move up to third in the Bundesliga and get back on course for an automatic Champions League spot with three matches left in the season.