The Brazilian ace scored a goal and assisted in another in a 3-0 victory over Olympique Marseille in the French first division.
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The move would end a turbulent spell at the club for the Argentine, who has fallen out with fans along on the way and provided fodder for the gossip columns thanks to his marriage to Wanda Nara, a media personality who also acts as his agent.
The Portuguese can expect a hostile reception in Valencia, who had to suffer 15 of his goals for Real Madrid and are returning to the Champions League for the first time in three years.
The win lifted Hamburg, who needed a relegation playoff to stay up last season, to seventh on six points.
A 'winning culture' may be one of the most over used terms in modern football but Real Madrid and Carlo Ancelotti proved on Saturday, at Liverpool's expense, that there truly is meaning and value in the concept.
Paris St Germain reached the Champions League semi-finals despite a 1-0 home defeat by holders Bayern Munich as they progressed on away goals
'We won at Tottenham away, Chelsea away, then Arsenal in the FA Cup, now this game today. What else does he have to do?'
Last season's runners-up Liverpool, big-spending French league champions Paris St Germain and Carlo Ancelotti's Napoli were thrown together in the pick of the groups while holders Real Madrid must face last season's semi-finalists AS Roma.
Britain's No 1 tennis player Andy Murray watched Neymar score twice.
Spain ended European champions Italy's world record 37-match unbeaten run as Ferran Torres scored twice in a 2-1 win at the San Siro stadium in an entertaining Nations League semi-final on Wednesday.
Less than a day after being knocked out the World Cup by Belgium, Brazilian striker Neymar said he will find it hard to return to club football.
Petr Cech will return in goal for Arsenal at HullCity on Saturday after missing the 1-1 Champions League draw at Paris St Germain in midweek.
Brazil against Argentina is a true clasico. The teams first met in 1914 and in the years since have established themselves as two of the most storied sides in world soccer. Together they have won seven World Cups.
New Chelsea signings David Luiz and Marcos Alonso are not ready for a first-team place in Sunday's Premier League clash with SwanseaCity, manager Antonio Conte said on Friday.
Neymar prompted more speculation with a brief Instagram video, showing a black-and-white image of himself in a shirt with the badge of Barcelona and a quote from the Bible, which was widely reproduced on news websites.
The former Barcelona forward, key to his country's hopes in Russia, came on as a halftime substitute and provided the moment of inspiration for win the game in the 69th minute.
Paris St Germain substitute Edinson Cavani, criticised by French media lacking composure in front of goal, responded in style to earn a 2-1 home win over Chelsea in their Champions League last-16 first leg on Tuesday.
Livepool striker and Dembele close in on Camp Nou move
With two days to go before his country meet Denmark in the first leg of their Euro 2016 playoff at the Friends Arena, Ibrahimovic also hinted that the two games against Sweden's Scandinavian rivals could be his last for the national team.
Cristiano Ronaldo has no plans to slow down and feels a decade younger than his 33 years
Liverpool's Brazil midfielder Philippe Coutinho is on the verge of signing for La Liga leaders Barcelona in a club-record deal, according to Spanish media reports.
Paris St Germain will play Borussia Dortmund and Barcelona were pitted against an unpredictable Napoli, while Chelsea were drawn against Bayern Munich. City, who will be at home in the second leg, have yet to beat the Spanish side with two draws and two defeats in their previous four meetings.
Franck Ribery, who has been shortlisted for the prestigious FIFA-Ballon d'Or award, was named French Player of the Year on Tuesday by France Football magazine.
Germany midfielder Julian Draxler has joined Paris St Germain on a four-and-a-half year contract from VfL Wolfsburg, the French champions said on Tuesday. The 23-year-old was a member of the victorious Germany squad at the 2014 World Cup. "For the first time in my career I will discover a new country, a new league and I am very proud to take this step in one of the best clubs in Europe," Draxler said in a club statement.
France coach Didier Deschamps confirmed his final Euro 2016 squad on Tuesday, including defenders Adil Rami and Samuel Umtiti in place of the injured Raphael Varane and Jeremy Mathieu. Liverpool centre back Mamadou Sakho was not included even though his 30-day provisional suspension for failing a drugs test expired last weekend. Hosts France geared up for the finals with a 3-2 victory over Cameroon in Nantes on Monday. They take on Scotland in Metz on Saturday.
PSG have set their sights on Messi, with PSG's players, coaches talking of their excitement about the prospect of bringing the Argentine to the French capital
Istanbul Basaksehir's players, closely followed by their opponents Paris St Germain, walked off the pitch during a Champions League soccer game on Tuesday after the Turkish club accused a match official of racism.
Defender Thiago Silva has criticised Brazil coach Dunga and star player Neymar after claiming neither of them told him he was no longer Brazil captain.
Gilberto Fleitas, the head of the investigations unit of the Paraguayan police, said Ronaldinho and his brother were taken into custody just hours after a judge refused to ratify a prosecutor's proposal for an alternative punishment.
News of all that's transpired on and off the football field.
Jorginho's first-half penalty earned Chelsea a 1-0 victory over Tottenham Hotspur in the Premier League on Thursday.
Javier Pastore and Edinson Cavani scored late as Paris St Germain ignored their fans' boos and recovered from a shaky start to beat visiting strugglers Evian Thonon Gaillard 4-2 on Sunday.
Poland midfielder Grzegorz Krychowiak has signed a five-year contract with Paris St Germain, the French champions said in a statement on Sunday.
Barcelona captain Lionel Messi says Neymar remains determined to return to the club
Tuchel has agreed an 18-month contract with the option of another year, the west London club announced.
Paris St Germain are hoping their Parc des Princes crowd will help them overturn a 3-1 deficit in their Champions League last-16 return leg against Real Madrid as they try to cope without the injured Neymar.
Brazil's Paris St Germain forward Neymar has had a successful operation
'There is a loss of camaraderie .. no one speaks unless i'ts work related .. it's like a laboratory where some rather deep scientific experiments abound.'
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