Among the others who have also been confirmed for the contest to be played in Navi Mumbai at the DY Patil Stadium are Javier Saviola, Phillip Cocu and Christian Karembeau.
The Spanish champions' new coach Bernd Schuster said the Argentine striker will be joining the club soon.
Porto's Radamel Falcao scored a hat-trick to help the newly-crowned Portuguese champions thrash Spartak Moscow 5-1 as goals flowed and South American players shone in Europa League quarter-final first leg ties on Thursday.
Two goals by Paraguay striker Oscar Cardozo helped Benfica to a 4-0 win over Hertha Berlin on Tuesday to clinch a place in the last 16 of the Europa League.
Javier Saviola and Oscar Cardozo scored two goals apiece and defender Luisao was also on target as Benfica thumped Everton 5-0 in the Europa League on Thursday.
Substitute Javier Saviola scored a late equaliser for champions Real Madrid as they could only draw 1-1 at promoted Valladolid in the Primera Liga.
Manchester United defender Gabriel Heinze, who has been out all season with a knee injury, was included in Argentina's World Cup squad.
Barcelona lead the Primera Liga on goal difference, ahead of title rivals Sevilla and Real Madrid.
Two goals from Eidur Gudjohnsen helped put Barcelona back to the top of the Primera Liga as they overcame Real Mallorca 4-1.
The list of the greatest living footballers as nominated by Brazilian legend Pele to mark the 100th anniversary of the foundation of FIFA.
The South Americans beat Tunisia 2-1 in the opening match of the Confederations Cup football tournament.
Javier Saviola and Wesley Sneijder set up champions Real Madrid for a laboured 3-1 victory over 10-man Almeria in the Primera Liga on Saturday.
Barcelona wasted a chance to go top of the Spanish Primera Liga by slumping to a 3-1 defeat at city rivals Espanyol.
Holders Barcelona must beat Levski Sofia to make sure of avoiding a shock exit from the UEFA Champions League.
Barcelona crushed Slovakia's Puchov 8-0 at the Nou Camp to go through 9-1 on aggregate.\n\n
\nArgentine forward Javier Saviola clinched a 1-0 win in Champions League Group A match.
Celtic will take a 1-0 lead to Barcelona after a tempestuous UEFA Cup fourth round, first leg clash on Thursday
He scored twice in a 4-2 win over Barcelona in the Spanish League.\n\n
The Argentinian forward scored a late goal at Turin in the first leg of the Champions League quarter-final.
The 23-year-old Brazilian was a constant threat in his second-half run-out, though, and scored from the penalty spot as the Catalans sneaked a 6-5 shoot-out win.
Give Messi time to decide on Argentina future, says Saviola
The policy of buying players cheap and selling them for a higher price a few years on is a business model that worked well for clubs like Atletico Madrid and FC Porto. With the transfer window open for the next few weeks, Rediff.com takes a look at clubs that made smart deals over the years.