Basel pulled off another huge Champions League upset with a 1-0 victory over Bayern Munich, while a stoppage-time goal from Andre Ayew gave Olympique Marseille a 1-0 win over Inter Milan in the first leg of their last-16 tie.
Brazil scored three superbly-taken goals, including a stunning Neymar effort, to beat feisty Austria 3-0 in sweltering conditions on Sunday and put the finishing touches to their impressive World Cup preparation.
Austria, who were undefeated in 10 qualifying games, were beaten 2-0 by old rivals Hungary in the opening match of Euro 2016 Group F on Tuesday.
Roundup of Champions League matches played on Wednesday night
Iceland's last-ditch defending, never-say-die attitude and a touch of luck was just too much for Austria's inexperienced side, beaten coach Marcel Koller said.
Napoli brush aside lowly Crotone to go third in Serie A.
Iceland snatched a stoppage-time winner to continue their fairytale story at Euro 2016 by making it through to the last 16 after a deserved 2-1 victory against Austria in their final Group F match on Wednesday.
Austria will double mark Portugal's Cristiano Ronaldo when the teams clash at Euro 2016 on Saturday, but fear that it could create space for his teammates to wreak havoc, Austria's captain Christian Fuchs said. The two nations had been considered the strongest teams in Group F, but the pressure on both has intensified after disappointing opening games. Portugal could only draw 1-1 with tournament debutants Iceland, while Austria lost 2-0 to unfancied Hungary. The prospect of stopping the three-times world player of the year has added to Austria's worries.
Hungary made their first appearance at a European Championship for 44 years a memorable occasion by grabbing their goal chances to score a 2-0 win over old rivals Austria in a Group F clash on Tuesday. Austria, riding a wave of national euphoria following an impressive qualifying run, were the better side for most of the game but left the pitch still dreaming of their first-ever win in the finals. The two teams, meeting for the 138th time, started the tournament with reasonable hopes of emerging from a group that also features Portugal and Iceland who meet later on Tuesday in St Etienne.
Manchester City came out on top in an epic Champions League battle against Monaco whereasAtletico Madrid beat hosts Bayer Leverkusen 4-2 in a topsy-turvy encounter.
A stunning free kick from Willian seven minutes from time gave Chelsea a nervy and hard-fought 2-1 UEFA Champions League Group G win over Dynamo Kiev on Wednesday to lift some of the gloom surrounding Stamford Bridge.
Manchester City must put a potentially ruinous fortnight behind them as they seek to reboot their faltering season with a big performance in their Champions League last-16, first leg trip to Dynamo Kiev on Wednesday.
Unai Emery's Villarreal were much improved in the second half and had spurned numerous chances before Moreno's leveller.
On a day of frenetic spending that took the Premier League total to a record far above one billion pounds ($1.29 billion), Antonio Conte's side also missed out on two of their other targets - Alex Oxlade-Chamberlain and Fernando Llorente.
Toni Kroos struck with a fierce long-range shot a minute from time to give Germany a 1-0 victory over Spain in a friendly between two injury-depleted European heavyweights in Vigo on Tuesday.