It was Messi's 30th goal in 39 competitive games against Atletico
'They were better than us for some spells and we know what awaits us over there' Valverde pointed to his team's sensational exit from last year's competition to AS Roma after a 4-1 cushion from the first leg and said they would be taking nothing for granted in Tuesday's return game at Anfield.
Jaume Costa atoned for giving away a first-half penalty when his strike five minutes from time rescued Villarreal a 1-1 draw against Eibar that put them fourth in La Liga on Sunday.
A summary of Sunday's action in Serie A and La Liga.
Delhi Dreams stormed into the final of the inaugural Champions Tennis League by overcoming a spirited Mumbai Tennis Masters by 27-21 in the best-of-five one-set clashes here at the Kalina University sports complex courts on Sunday night.
"I don't know how this affects my future," Valverde said.
Dempo edged past a JCT by a solitary goal in Margao on Friday and moved to the top of the standings in the 7th edition of the National Football League.\n\n
La Liga leaders Barcelona beat Real Madrid 1-0 to all but knock their rivals out of the title race on Saturday, while second-placed Atletico Madrid stayed seven points behind the Catalans with a 2-0 win at Real Sociedad on Sunday.
A delightful flick and volley from Neymar allowed him to complete a double as Barcelona beat Villarreal 3-0 to go three points clear at the top of La Liga ahead of Real Madrid's clash with Sevilla later on Sunday.
Images from La Liga matches played on Sunday
Paris St Germain suffered their first defeat of the season when they were beaten 2-0 at Stade Rennais on Sunday to drop their first Ligue 1 points of the season.
Barcelona coach Luis Enrique said he believes Lionel Messi will sign a new contract with the Spanish champions despite reports the five times World Player of the Year is stalling over a new deal.
Lionel Messi squeezed home a stoppage-time penalty to grab a 3-2 win for champions Barcelona at Valencia in a thrilling and controversial La Liga match on Sunday.
Spain's talisman Rafael Nadal sealed a sixth Davis Cup title for his country on Sunday when they beat Canada 2-0 in the final of the revamped event.
A dominant yet wasteful Real ravaged their rivals in the first half while spurning a string of clear chances at the Santiago Bernabeu.
Following the incident, all flights at Stansted had to be temporarily grounded, according to British media reports.
News of all that's transpired on and off the football field
A dominant Delhi Dreams registered their second successive win in the Champions Tennis League (CTL), defeating a fighting Mumbai Tennis Masters 27-19 in a North Group match in New Delhi on Tuesday night.
Images from Tuesday's action in the UEFA Champions League.
The win increased Zinedine Zidane's side's advantage at the top of the standings to six points
Rafael Nadal fired hosts Spain into the Davis Cup final as he joined Feliciano Lopez to win a thrilling late-night doubles and seal a nail-biting 2-1 victory over Britain on Saturday.
David Ferrer toppled Philipp Kohlschreiber in a thrilling five-hour marathon decider as Spain roared back from 2-1 down in their Davis Cup tie against Germany to reach the semi-finals on Sunday.
Paris Saint Germain's Neymar, Laywin Kurzawa and Leandro Paredes as well as Marseille's duo of Dario Benedetto and Jordan Amavi were given their marching orders after rival players threw punches and kicks at each other.
La Liga leaders Barcelona won a tight and tense 'Clasico' 1-0 at Real Madrid on Saturday, beating their great rivals at their Bernabeu home for the second time in four days and moving a staggering 12 points clear of them in the standings.
Images from football matches played across Europe.
Barcelona rarely looked capable of repeating their heroic comeback in the last 16 against Paris St Germain.
Imperious Liverpool extended their Premier League home winning streak against Arsenal to six on Saturday with an easy 4-0 victory that lifted them to second in the table.
Barcelona rode their luck to come from behind and win 2-1 at Real Sociedad on Saturday, continuing to banish their awful record in San Sebastian and maintaining their perfect start to the La Liga season.
Barcelona are in the middle of an injury crisis as they head to Valencia for Saturday's La Liga game looking to keep up with pacemaking pair Atletico Madrid and Real Madrid. Without injured goalkeeper Jasper Cillessen and right back Sergi Roberto for the last two games, Barca will also be missing defenders Jordi Alba and Gerard Pique after both were hurt in Wednesday's 4-0 win over Manchester City in the Champions League. Pique sprained his right ankle while Alba injured his left hamstring and both are out until November.
Griezmann goal earns Atletico first win of season
Luis Enrique is set to leave a mixed legacy when he departs Barcelona but the coach can go out on a high by lifting a third consecutive King's Cup when his side meet Alaves in Saturday's final in Madrid.
Real Madrid defender Nacho was the unlikely hero as they snatched a 1-0 win at Real Valladolid on Sunday to capitalise on Barcelona's defeat at Valencia this weekend and move three points clear of their rivals at the top of La Liga. Serie A leaders Juventus suffered a shock 2-1 defeat at Napoli on Sunday, with coach Maurizio Sarri returning to his former club for the first time, though Cristiano Ronaldo still managed to score for an eighth league game in a row for the visitors.
Valencia's Paco Alcacer and Dani Parejo both hit doubles in a surprise 5-1 away thrashing of high-flying Celta Vigo in La Liga on Saturday.
Pep Guardiola's formidable managerial skills will be put to the test again when his stuttering ManchesterCity side visit his former club Barcelona in a top-of-the-bill Champions League clash on Wednesday.
Pedro hit a first-half hat-trick as Barcelona cruised into the last 16 of the King's Cup with a 8-1 second leg demolition of lower league Huesca at the Camp Nou on Tuesday.
Paris St Germain's league record 36-game unbeaten streak came to an abrupt halt when they lost 2-1 at Olympique Lyonnais on Sunday.
Bollywood stars up their fashion game at IIFA!
A mesmeric Lionel Messi helped Barcelona to come from behind and beat Sevilla 2-1 in a thrilling encounter on Sunday as the champions kept the pressure on La Liga leaders Real Madrid, who saw off Leganes 3-0 thanks to a double from Gareth Bale.
Messi, who has struggled for form in recent weeks due to a niggling injury, looked on a mission to grab the winner and after twice coming close he completed his treble to put Barca ahead in the 85th minute, reacting quickly to a poor Sevilla clearance to dink the ball over goalkeeper Tomas Vaclik.