The to were shortlisted for FIFA's World Player of the Year award, which will be announced on December 19.
Brazilian midfielder Emerson will return to Italy to play for AC Milan after just one season with Real Madrid.
A hat-trick from Giovani dos Santos helped Barcelona to a 5-3 victory away to relegated Real Murcia.
Real Madrid moved closer to retaining their Primera Liga title with a 2-0 win away at Racing Santander.
Barcelona failed again to put pressure on leaders Real Madrid after being held to a 0-0 draw at home by city rivals Espanyol in the Primera Liga on Saturday. The Champions League semi-finalists have only managed one win in their last eight league matches. They stay second with 61 points, eight short of Real who can extend their lead at the top to 11 with a win at fifth-placed Racing Santander on Sunday.
Barcelona and Villarreal failed to put the pressure on leaders Real Madrid as they dropped points in the Primera Liga.
Real Madrid were held to a 1-1 draw at Real Mallorca in the Primera Liga on Saturday.
Real Madrid beat Sevilla 3-1 at the Bernabeu to move six points clear at the top of the Primera Liga.
Ajax Amsterdam's Netherlands defender John Heitinga has agreed to sign a five-year deal with Atletico Madrid, he told Tuesday's De Telegraaf newspaper.
Barcelona closed to within four points of Real Madrid at the top of the La Liga after the leaders lost 3-2 at home to Valencia.
Real Madrid lost 1-0 against Deportivo Coruna in La Liga as they failed to break their jinx at the Riazor.
Zambrotta, 29, has agreed a four-year contract while 34-year-old Thuram has negotiated a two-year deal with the Spanish club.
Barcelona closed to within two points of leaders Real Madrid after thumping Levante 5-1.
A last-gasp 4-3 victory over Espanyol put them top of the Primera Liga for the first time since September.
Second-placed Barcelona failed to keep the pressure on leaders Real Madrid after scrambling a 1-1 draw at Sevilla in the Primera Liga.
Real Madrid's eight-match winning run in the Primera Liga came to an end when they lost 2-0 to Almeria.
Real Madrid lost 1-0 at home to Real Mallorca in the King's Cup last-16 and went out of the tournament 3-1 on aggregate.
The Liverpool striker agreed personal terms and a three-year contract with Spanish club Valencia.
Samuel Eto'o scored two late goals for Barcelona in a 4-0 romp at home to promoted Real Murcia in the Primera Liga on Saturday.
Ruud van Nistelrooy has signed a one-year contract extension that keeps him with Real Madrid until 2010.
Ukraine champions Shakhtar Donetsk dented Sevilla's bandwagon as the UEFA Cup holders wobbled before securing a 2-2 draw.
Samuel Eto'o led Barcelona to only their second away win of the season in a 3-0 victory over Valencia.
Real Madrid charged seven points clear at the top of the Primera Liga after a 1-0 win at Athletic Bilbao.
Villarreal missed their chance to stay in touch with Real Madrid at the top of the Primera Liga when they went down 2-0 at Valladolid on Sunday. The defeat kept Manuel Pellegrini's side level with Barcelona on 28 points in third spot in the table and four adrift of leaders Real, who won 3-1 at home to Racing Santander on Saturday.
The former England captain scored on his return to the team after a month on the sidelines to inspire Real Madrid to a 2-1 comeback win at Real Sociedad.
Leaders Real Madrid were held to a 1-1 draw away to promoted Real Murcia in the Primera Liga on Saturday, allowing arch-rivals Barcelona to close to within two points in the standings.
Real Madrid extended their lead at the top of the Primera Liga with an unconvincing 4-3 home victory over Real Mallorca at the Bernabeu on Sunday.
Getafe returned to haunt Barcelona as they condemned Frank Rijkaard's side to a 2-0 defeat in the Primera Liga on Saturday. The last time Barca visited the Coliseum six months ago Getafe knocked them out of the King's Cup in the semi-finals by overturning a 5-2 first-leg deficit with a stunning 4-0 win.
Barcelona lead the Primera Liga on goal difference, ahead of title rivals Sevilla and Real Madrid.
Sevilla earned a 2-0 home victory over leaders Real Madrid in a pulsating Primera Liga match.
The Catalans made a lethargic start and fell behind in the 16th minute when striker Joseba Llorente bundled the ball into the net but they salvaged a point when Ronaldinho equalised with a neat finish just before halftime.
Real Madrid scored two late goals to secure a 3-1 home win over Deportivo Coruna in the Spanish Primera Liga.
Champions Barcelona scrambled a barely deserved 1-1 at Getafe, in the Primera Liga.
Villarreal are a point behind in second after overcoming Barcelona 3-1 at home, and were joined on 18 points by Valencia.
Lionel Messi struck late to help Barcelona seal a place in the King's Cup final on Wednesday, a 1-1 draw at Real Mallorca completing a 3-1 aggregate victory for the Primera Liga leaders. Barcelona will play Athletic Bilbao in the May 13 final in Valencia after the Basque club beat Sevilla 3-0 at home to overturn a 2-1 defeat from last month's first leg.
Second-half strikes from Ruud van Nistelrooy and Gonzalo Higuain earned Real Madrid a 2-0 win at home to Recreativo Huelva.
Lionel Messi proved too hot to handle for Real Zaragoza as he inspired Barcelona to a 4-1 home victory with two goals in the Primera Liga.
Espanyol fought back from a goal down to beat Sevilla 2-1 at home in the Primera Liga on Sunday, denying the Andalucians first place in the standings.
Javier Saviola and Wesley Sneijder set up champions Real Madrid for a laboured 3-1 victory over 10-man Almeria in the Primera Liga on Saturday.
The 33-year-old Brazilian fullback extended his existing deal for another year until June 2008.