Lionel Messi has added another record against his already legendary name.
Messi scored twice and created goals for Arturo Vidal and Luis Suarez as champions Barca moved top of the table with 22 points from 10 matches.
Liverpool manager Brendan Rodgers says his side must tighten up defensively after a 5-3 victory over Stoke City on Sunday in which Daniel Sturridge resumed his lethal strike partnership with Luis Suarez.
Real Madrid's Sergio Ramos scored in the 90th minute to hold FC Barcelona to a 1-1 draw at the Camp Nou on Saturday.
A summary of Sunday's action in the FIFA World Cup qualifiers across Europe.
Live updates of Saturday's World Cup matches.
Adidas stopped short on Thursday of ending its sponsorship deal with Uruguay's Luis Suarez after FIFA banned him for nine matches for biting an Italy defender, but the German sportswear firm said it would not use him in any further World Cup marketing.
Alaves reached the King's Cup final for the first time in their 96-year history as Edgar Mendez's 83rd-minute strike saw off Celta Vigo 1-0 in the semi-final second leg on Wednesday to take the Basque side through 1-0 on aggregate.
Neymar scored a spectacular goal as Barcelona came from behind to beat Paris St Germain 3-1 in their UEFA Champions League match.
Tuesday's match was the latest masterclass from the South American trio, known in Spain as 'MSN', whose goals have put Barca on the brink of repeating 2009's treble of Champions League and Spanish league and Cup triumphs, the only time a La Liga club have achieved the feat.
Barcelona named former Athletic Bilbao coach Ernesto Valverde on Monday as the successor to Luis Enrique and he will take charge of the La Liga runners-up on a two-year contract.
Barcelona came through a testing local derby at Espanyol, winning 3-0 to cling to their slender lead at the top of La Liga after rivals Real Madrid had set the challenge by beating Valencia 2-1 in the earlier kick-off.
Dheeraj Singh Moirangthem left for a trial at Scottish Premiership club Motherwell FC. His training sting is starting from Thursday.
Barca dominated possession and Luis Suarez had several early chances but it was Villarreal who took the lead with Denis Cheryshev redirecting a Mario Gaspar shot past keeper Claudio Bravo on the half hour.
Barcelona twice threw away the lead to draw 3-3 at Levante on Tuesday in a potentially fatal blow to their chances of winning the La Liga title.
Images from Wednesday's action in the Champions League.
A red hot Luis Suarez scored four goals and contributed three assists as Barcelona's stuttering La Liga title charge sparked back to life with a spectacular 8-0 thrashing of Deportivo La Coruna on Wednesday.
IMAGES from Serie A matches played in Italy on Wednesday.
Barcelona will attempt to give Luis Enrique his 100th victory in his 125th game in charge of the team when they play at Athletic Bilbao in la Liga on Sunday. A former Barca player, the 46-year-old led them to a La Liga, King's Cup and Champions League treble in his first year in charge and the domestic double last season. The Catalans started the campaign with a 5-0 aggregate triumph over Sevilla in the Spanish Super Cup and a 6-2 victory over Real Betis in La Liga.
With supporters not allowed to attend matches and even the numbers of media tightly limited, there will be no boost in business for local bars and restaurants.
Goals from Matti Steinmann (6th) and Anthony Pilkington (68th) secured the victory for SCEB
Images from the UEFA Champions League matches played on Wednesday night.
News of all that's transpired on and off the football field
Luis Suarez returned from injury to give Uruguay a 1-0 lead in the first half in their World Cup Group D match against England on Friday.
IMAGES from the Group A match played between Russia and Uruguay in Samara on Monday
Barcelona dealt a stinging blow to Real Madrid's title hopes when Luis Suarez and Neymar continued their scintillating form to fire the champions to a stunning 4-0 victory in the La Liga 'Clasico' on Saturday.
Roma teenager Afena-Gyan plays down apparent racist remark.