The Belgians finished first in pool A and hence will be teamed against India.
India put up a dominating performance to beat Malaysia 4-1 in the bronze medal play-off match on Sunday and finish at third position in the Four Nations Invitational Tournament in Melbourne.
Indian men's hockey team finished a disappointing fourth at the Commonwealth Games as it struggled to breach a stout England defence to lose the bronze medal match 1-2, in Gold Coast, on Saturday.
India's report card on the seventh day of the 2016 Olympics.
A nervy India squandered a one-goal advantage as they allowed Canada to stage a fightback with a late strike and earn a 2-2 draw in their final men's hockey pool game of the Rio Olympics Games.
India lifted its sagging morale as Sania Mirza and Rohan Bopanna cruised into the semi-finals while pugilist Vikas Krishan advanced to the quarters on a day the shooters, archers, shuttlers and track and field athletes suffered reverses at the Rio Olympics.