The victory saw Spain finish top of League A4 with 11 points after six games, joining France in the final four tournament, which will take place in October 2021.
As Barca prepare for a trip to Madrid to play Rayo Vallecano on Saturday, they are still reeling from Tuesday's 3-2 Champions League reverse at Paris St Germain, when their defence was badly exposed by the Ligue 1 title holders.
Barcelona had to come from a goal down to rescue a 1-1 draw at mid-table Levante on Sunday, leaving Atletico Madrid with a chance to go top of La Liga.
The injury will put Valencia midfielder Edu out of action for most of the season.
Tottenham Hotspur winger Gareth Bale joined Real Madrid for a record 100 million euros while Lionel Messi showed the talent he will be up against in La Liga when the Argentine hit a hat-trick in Barcelona's 3-2 win over Valencia.
Aston Villa beat Crystal Palace 1-0 to win a Premier League match for the first time since August while a late goal from Paul Dummett earned a 3-3 draw for Newcastle United against Manchester United on Tuesday.
The 22-year-old left winger has been the outstanding Spanish player in the Primera Liga this season.
A Marco Asensio-inspired Real Madrid crushed Eibar 3-0 to close the gap on La Liga leaders Barcelona to five points on Sunday, with Karim Benzema starting on the bench.
Nine-times winners Real Madrid will play Manchester United in the last 16 of the Champions League after the draw was made at UEFA's headquarters in Switzerland on Thursday.
A 5-1 victory enabled them retain the top spot in the Primera Liga.
Portugal's Nani is poised to make his 99th appearance for his country in a crunch clash with Hungary on Wednesday and has been an automatic choice for the Selecao for a decade, yet there is a feeling the forward has not fulfilled his dazzling potential. Nani, blessed with searing pace, mesmerisingly quick feet and more tricks than a children's entertainer, will turn 30 in November and Euro 2016 could give the Fenerbahce star the platform for a transfer back to one of Europe's elite leagues. Scorer of Portugal's sole goal at the tournament - a neat finish in a 1-1 draw with Iceland - Nani has so far outperformed his captain and former Manchester United team mate Cristiano Ronaldo although he should have added to his tally of 18 international goals in Saturday's stalemate against Austria.
Beckham was whistled and jeered by Valencia fans for a mediocre display during a pre-season friendly.\n\n
Jose Mourinho's Chelsea turned from domestic whipping boys back to European stalwarts on Wednesday, beating his former club Porto 2-0 to top Champions League Group G.
Antonio Valencia's early thunderbolt put Manchester United en route to a 4-0 Premier League victory over Everton on Sunday, but they needed a flurry of late goals to finally subdue their unfortunate visitors.
Reigning champions Real Madrid took advantage of Valencia's defeat against Deportivo to move up to second.
Second-placed Tottenham Hotspur kept up the distant chase of Premier League leaders Chelsea with a hard-earned 2-1 victory over Southampton to cut the gap to 10 points on Sunday.
Ferrari's Fernando Alonso rewrote the Formula One form book by winning his home Spanish Grand Prix for the second time on Sunday.
Barcelona closed in on the La Liga title by thrashing local rivals Espanyol 5-0 on Sunday as Atletico Madrid dropped out of the race after losing 2-1 at Levante and Real Madrid beat Valencia 3-2.
The Portuguese is reported to be demanding another new deal to bring his salary in line with Lionel Messi and Neymar, the top two earners in world soccer.
Barcelona midfielder Xavi has withdrawn from the Spain squad to play Uruguay this week because of a hamstring problem, the Spanish football federation (RFEF) said on Monday.
La Liga champions Barcelona stayed on the heels of leaders Real Madrid by coasting to a 3-0 home win over Athletic Bilbao on Saturday as Lionel Messi became the club's top scorer from free kicks.
The Spanish League leaders slipped to a 2-0 defeat at home to Real Mallorca.
Check out the top footballers of the weekend...
Qatari-backed Paris St Germain's mission to be considered one of Europe's top clubs faces its toughest test yet when they host Barcelona in an intriguing Champions League quarter-final first leg on Tuesday.
Real Madrid's faint hopes of retaining their La Liga title receded further when Kaka was sent off and they drew 0-0 at struggling Osasuna on Saturday, while Valencia climbed to seventh with a 2-0 win over Sevilla.
Britain number one Andy Murray has overtaken 14-time Grand Slam champion Rafael Nadal to claim the third spot in the ATP world rankings.
Cristiano Ronaldo scored twice as Real Madrid beat Athletic Bilbao 4-2 in a thrilling match at the Bernabeu to move within a point of leaders Barcelona in La Liga on Saturday.
Morata, who had scored his first goal for the club in last week's 2-0 win over Villarreal, rose to head home from close range on the half-hour mark following a corner which had been flicked on by Atleti captain Diego Godin.
Valencia, Ajax Amsterdam and Inter Milan clinched their places on Wednesday night.
Paris St Germain striker Zlatan Ibrahimovic was suspended for two games by UEFA on Wednesday for his sending off in the Champions League last 16 first leg match with Valencia, the governing body said.
'General Secretary Xi Jinping has greenlighted a brutal campaign of repression against Chinese Muslims, a human rights violation on a scale we haven't seen since World War II. Now, the PLA has escalated border tensions with India'
