Girondins Bordeaux survived a second-half scare to grab a 2-1 win over Olympiakos Piraeus on Wednesday and give France a second team in the Champions League quarter-finals.
Costa Rica secured a place in the World Cup quarter-finals for the first time on Sunday after beating Greece 5-3 on penalties after the teams finished level at 1-1 after extra time, the Central Americans playing for almost an hour with 10 men.
Five-times European champions Barca, with their trident of Lionel Messi, Luis Suarez and Neymar subdued, have not exited in the last 16 since going out to Liverpool in the 2006/07 season and the score equalled their worst Champions league loss.
Olympiakos Piraeus secured a surprise 3-2 victory over last year's Champions League runners-up Atletico Madrid to make a dream start to their Group A campaign on Tuesday.
Benfica coach Rui Vitoria faces another test of his powers of improvisation as he tries to patch up a team without topscorer Jonas against Bayern Munich on Wednesday.
Atletico Madrid striker Antoine Griezmann struck twice as the Spanish side outclassed hapless Olympique de Marseille 3-0 on Wednesday to win the Europa League for the third time.
Colombia marked their return to the World Cup after a 16-year absence with an attacking display that earned a 3-0 victory over Greece on Saturday, and the early initiative in what looks to be a really tight Group C.
Juventus did the bare minimum as they scraped into the Champions League knockout stage on Tuesday with a 0-0 draw at home to Atletico Madrid, a result which also suited the Spaniards who topped the group.
Bayern Munich booked their fifth successive Champions League semi-final spot with a 2-2 draw at Benfica on Wednesday to seal a 3-2 aggregate victory that kept the Germans on course for a treble of titles.
Germany's Thomas Mueller struck twice as the nervy world champions kicked off their Euro 2016 qualifying campaign with a 2-1 victory over Scotland on Sunday.
Barcelona first struggled to come to terms with their shock 4-0 defeat to Paris St Germain in the Champions League last 16 first leg but have sparkled in their last two games and are daring to believe they can defy history by reaching the quarter-finals.
European heavyweights Barcelona, Bayern Munich, Juventus and Paris St Germain all maintained their leads and Benfica toppled Sporting Lisbon.
France's hopes of reaching the World Cup finals are hanging by a thread after a 2-0 first-leg defeat away to Ukraine in their playoff on Friday while Cristiano Ronaldo's late winner gave Portugal the edge against Sweden.
The Greek league leaders confirmed the move but did not give financial details. Local media said Toure would be paid around 2.5 million euros ($2.9 million) for one season.
Cristiano Ronaldo scored two stunning goals and took his international tally to 70 as he led Portugal to an emphatic 3-0 win over Hungary in a World Cup qualifier on Saturday.
News of all that's transpired on and off the football field
Schuerrle hits treble for the world champs; Lewandowski helps Poland thrash Georgia