French Open and Wimbledon champion Alcaraz, who won both of his previous meetings with Sinner this year, recovered from a slow start to wrap up victory in three hours, 21 minutes and improve his head-to-head record with the Italian to 6-4.
Nadal needed all his experience to keep Pouille at bay in the decider and the match looked to be heading for another tiebreak before he pounced to break Pouille's serve for the first time to go 6-5 up in the third.