World Cup favourites Spain crashed to a shock 1-0 defeat to unfancied Switzerland in their opening game of the tournament at durban on Wednesday.
Spain coach Luis Aragones announced a 23-man squad for next month's World Cup in Germany on Monday.
Wounded VfL Wolfsburg, who drew 1-1 with Hanover 96 on Saturday after being crushed 5-1 by Bayern Munich last week, will meet Manchester United in Wednesday's Champions League game.
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A stoppage-time goal by substitute Haris Seferovic gave Switzerland a 2-1 World Cup Group E win over Ecuador on Sunday.
Bayern Munich striker Robert Lewandowski netted the Bundesliga's fastest hat-trick on his way to a sensational five-goal haul as a halftime substitute in their 5-1 demolition of VfL Wolfsburg on Tuesday.
Angel Di Maria scored in the dying minutes of extra-time to give Argentina a 1-0 victory over Switzerland and a place in the last eight of the World Cup in Sao Paulo on Tuesday.
Second-placed VfL Wolfsburg breathed new life into the Bundesliga title race with a 4-1 win over leaders Bayern Munich, who lost their unbeaten record in a dramatic restart to the league after the winter break on Friday.
Free-flowing France blew away in-form Switzerland with a three-goal first-half barrage en route to a thumping 5-2 World Cup Group E victory on Friday that virtually assures them qualification to the second round.
Thomas Mueller scored twice as Bundesliga leaders Bayern Munich came from a goal down to beat Hanover 3-1 on Saturday and stretch their advantage at the top to 11 points after VfL Wolfsburg slumped to a 1-0 loss at Augsburg.
News of all that's transpired on and off the football field
Cristiano Ronaldo's fifth Champions League hat-trick inspired Real Madrid to a 3-0 comeback victory over VfL Wolfsburg on Tuesday that clinched a place in the semi-finals for a sixth successive season.
La Liga champions Barcelona began the new campaign with a 3-0 win over Alaves on Saturday with the help of a spectacular under-the-wall free kick from Lionel Messi, who scored twice, and a curling shot from substitute Philippe Coutinho.
Napoli put a foot in the Europa League semi-finals with a perfectly crafted 4-1 win at VfL Wolfsburg on Thursday as Marek Hamsik scored twice in an Italian masterclass to bring cheer to beleaguered coach Rafael Benitez.
VfL Wolfsburg reached the Champions League last 16 and dealt a knockout blow to Manchester United with a 3-2 victory to claim top spot in Group B and condemn their opponents to the Europa League on Tuesday.
Liverpool failed to muster a single shot on target in a Champions League game for the first time since a 1-0 defeat to Benfica in February 2006.
Wolfsburg shock Real Madrid 2-0 to crown big European night.
Sweden striker Zlatan Ibrahimovic crowned a triumphant homecoming with a second-half goal as Paris St Germain crushed Malmo 5-0 on Wednesday to book a place in the last 16 of the Champions League.
images from the UEFA Champions League matches played across Europe on Wednesday
Anthony Martial went from villain to hero as his second-half equaliser earned Manchester United a deserved point in a 1-1 draw against CSKA Moscow in Champions League Group B on Wednesday.
Photos from the Champions League matches played on Wednesday.
Photos from the Champions League matches played across Europe on Tuesday