Murray, bidding to become the first British men's singles champion at Wimbledon for 75 years, had no answer to the Spaniard's sustained brilliance, making a string of unforced errors as the match slipped away from him.
Murray looked completely focused and there were none of the desperate pleading looks towards his family or the berating of himself after an error that all-too often upset his equilibrium.
It was tight again in the early stages of the second set but the match seemed to turn in the fourth game. Nadal was struggling at 15-30 and 2-1 down when the pumped-up Briton sent an easy forehand long.
Instead of pressuring for the break, Murray went on to lose the game, sparking a run of seven successive games for the Spaniard that won him the second set and gave him the early initiative in the third.
"He had an important mistake, easy forehand, that was probably one of the turning points of the match," Nadal said.
Despite sending five rackets out to be restrung, Nadal maintained his relentless forehand assault while Murray's radar was faulty and another break and superb serving enabled Nadal to sweep through for a 2-1 lead.
Murray needed to rediscover his early fire but he was ragged again in the first game of the fourth set when an inconclusive volley allowed Nadal to send a backhand pass screaming under his nose on the way to another early break.
Murray never looked capable of stopping the flow as Nadal, who also beat him in the French Open semi-finals this year, cranked up the pressure with his relentless accuracy and variety of shot.
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