Cibulkova sprung into life after a first-set pummelling by world number one Caroline Wozniacki to produce some devastating ground strokes of her own and will test all of Sharapova's skill.
First up on Centre Court is Sabine Lisicki of Germany, seeking to become the first wildcard to win the women's singles, against ninth seed Marion Bartoli of France who is fresh from a morale-boosting win over Serena.
Over on Court One, last year's surprise semi-finalist Petra Kvitova of the Czech Republic plays Bulgarian 32nd seed Tsvetana Pironkova, who also upset the odds to reach the last four in 2010.
Finally, the unseeded Tamira Paszek of Austria takes on the noisy Azarenka.
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