Scientists have developed the world's smallest superconductor -- less than one nanometre wide -- which could be used for making miniature electronic devices.
The superconductor, a sheet of four pairs of molecules, provides the first evidence that nanoscale molecular superconducting wires can be fabricated, journal Nature Nanotechnology reported.
"Researchers have said that it's almost impossible to make nanoscale interconnects using metallic conductors because the resistance increases as the size of wire becomes smaller. The nanowires become so hot that they can melt and destruct," said lead author Saw-Wai Hla from the Ohio University.
"This issue, Joule heating, has been a major barrier for making nanoscale devices a reality but we've opened up a new way to understand this phenomenon, which could lead to new materials that could be engineered to work at higher temperatures," he said. Superconducting materials have an electrical resistance of zero, and so can carry large electrical currents without power dissipation or heat generation.
"Superconductivity was first discovered in 1911, and until recently, was considered a macroscopic phenomenon. The current finding suggests, however, that it exists at the molecular scale, which opens up a novel route for studying this phenomenon," Hla said. Superconductors currently are used in applications ranging from supercomputers to brain imaging devices.
In the new study Hla's team examined synthesised molecules of a type of organic salt, (BETS)2-GaCl4, placed on a surface of silver. Using scanning tunnelling spectroscopy, the scientists observed superconductivity in molecular chains of various lengths.
For chains below 50 nanometres in length, superconductivity decreased as the chains became shorter. However, the researchers were still able to observe the phenomenon in chains as small as four pairs of molecules, or 3.5 nanometres in length, Science Daily said. To observe superconductivity at this scale, the scientists needed to cool the molecules to a temperature of 10 Kelvin.
Warmer temperatures reduced the activity. In future studies, scientists can test different types of materials that might be able to form nanoscale superconducting wires at higher temperatures, Hla said.
The study also is noteworthy for providing evidence that superconducting organic salts can grow on a substrate material.
Image: Saw-Wai Hla
