Valencia's Pablo Piatti scored twice to set up a meeting with Barcelona in the King's Cup semi-finals after helping his side to a 7-1 aggregate win at city rivals Levante on Thursday.
Lionel Messi scored four as Barcelona came from behind to thrash Valencia 5-1 at home, closing the gap on La Liga leaders Real Madrid back to 10 points on Sunday.
Antoine Griezmann scored twice off the bench as Atletico Madrid sealed a place in the King's Cup quarter-finals with a 3-0 win at home to Rayo Vallecano on Thursday while Valencia also advanced with victory by the same scoreline at Granada.
Valencia lost ground in the battle with Atletico Madrid and Sevilla for third place in La Liga when they conceded a late Aritz Aduriz equaliser in a bad-tempered 1-1 draw at Athletic Bilbao on Thursday.
Valencia's Paco Alcacer, Dani Parejo and Pablo Piatti found the target as they took full advantage of the first-half dismissal of Malaga's Sergi Darder to win 3-0 at the Mestalla on Friday.
Atletico Madrid knocked Barcelona off the top of La Liga, for a day at least, as a second-half strike by Koke earned a 1-0 victory over a stubborn Malaga side on Saturday.
Lionel Messi squeezed home a stoppage-time penalty to grab a 3-2 win for champions Barcelona at Valencia in a thrilling and controversial La Liga match on Sunday.
Fiorentina fell behind to a spectacular scissors-kick goal from Pandurii's Eric Pereira before hitting back in the last five minutes to win 2-1 on Thursday and lead a charge of teams into the Europa League knockout stages.
Barcelona suffered a first home defeat of the season when they lost 3-2 against Valencia after finishing with 10 men in La Liga on Saturday, leaving the door open for Madrid rivals Atletico and Real to move above them.
A late header by Imanol Agirretxe gave Real Sociedad, who are without a coach, a 2-1 victory over 10-man Atletico Madrid in La Liga on Sunday.
Barcelona's Lionel Messi was at the heart of another devastating attacking show.
Lionel Messi produced a vintage second-half performance to help Barcelona to a 4-1 win over local rivals Espanyol on Sunday which saw the champions cut the gap on La Liga leaders Real Madrid to three points.
An insatiable Lionel Messi hit a hat-trick as Barcelona hammered Espanyol 5-0 in a local derby on Saturday to make it three wins from three and take full advantage after Liga champions Real Madrid were held to a 1-1 draw at home to Levante.
A summary of sports events and sports persons, who made news on Friday
