Liverpool, who enjoyed a 2-1 Premier League victory at Chelsea earlier this month, doubled their lead shortly after when Bellamy's free kick was headed in by Kelly.
The result put the spotlight back on Chelsea's Villas-Boas whose side have endured a worrying slump in form after an encouraging start to the season.
"It's a competition that we wanted to go all the way through but we are out in the quarter-finals at home so we should be critical with ourselves and shouldn't accept it," Villas-Boas told Sky Sports. "But we have to move on and reunite."
While captain Steven Gerrard is still injured for Liverpool, his cousin Anthony had a good night, scoring Cardiff's second goal against Blackburn after Kenny Miller had given the Welsh club the lead in the 19th minute.
Liverpool fans hold up a banner during the League Cup quarter-final between Chelsea and Liverpool on Tuesday
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