Nadal made a winning return on Friday after more than a month out injured when he cruised past Ruben Bemelmans to give his side a 2-0 lead that Belgium were ill-equipped to overhaul.
Lopez is already casting his mind ahead to a quarter-final against the United States, after Bob and Mike Bryan gave Jim Courier's side a 2-1 lead against Chile in Santiago.
"The match against the United States will be extremely tough," he told reporters.
"They are one of the toughest teams we could get playing away, with Andy Roddick and John Isner and the world's best doubles team," he added.
Sweden took an unassailable lead against a below-strength Russia with Simon Aspelin and Robert Lindstedt beating Igor Kunitsyn and Dmitry Tursunov while in Buenos Aires, Argentina also established a 3-0 lead.
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