Holders Spain joined the Americans in the quarter-finals as they moved 3-0 ahead against Kazakhstan in Oviedo to give new captain Alex Corretja a pleasing start in the absence of Ferrer and Rafa Nadal.
Last year's runners-up Argentina and Czech Republic also moved smoothly through with a day to spare against Germany and Italy respectively.
Japan have an uphill battle in their first World Group tie for 26 years, 2-1 down at home to Croatia.
Nikolay Davydenko and Mikhail Youzhny kept Russia alive in their tie in Austria with victory in Saturday's doubles meaning the visitors now trail 2-1.
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