Real scored six goals without reply when they played Ajax home and away in last season's group stage.
The Dutch club have since brought in former Barca player Frank De Boer to replace Martin Jol as coach but are still a shadow of the side that won the Champions League in 1995 and lost to Juventus on penalties in the final the following year.
Ajax failed to beat visiting Olympique Lyon in their group opener and have recorded consecutive draws against PSV Eindhoven and Twente Enschede in the Dutch league as well as struggling to a 3-1 Cup win against the amateurs of Noordwijk.
Probable teams:
Real Madrid: 1-Iker Casillas; 4-Sergio Ramos, 18-Raul Albiol, 19-Raphael Varane, 17-Alvaro Arbeloa; 14-Xabi Alonso, 6-Sami Khedira; 10-Mesut Ozil; 22-Angel Di Maria, 9-Karim Benzema, 7-Cristiano Ronaldo.
Ajax: 1-Kenneth Vermeer; 2-Gregory van der Wiel, 4-Jan Vertonghen, 3-Toby Alderweireld, 5-Vurnon Anita; 8-Christian Eriksen, 6-Eyong Enoh, 16-Theo Janssen, 10-Siem de Jong; 7-Miralem Sulejmani, 9-Kolbeinn Sigthorsson.
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