There was more positive news on Andres Iniesta's calf injury when the Spain midfielder, who missed last week's first leg, took part in Sunday's training session.
Real will be without Pepe for Tuesday's game and defender Sergio Ramos is also suspended. Mourinho, who was sent from the bench for protesting Pepe's dismissal, will have to watch from the stands.
"Madridismo always believes in comebacks," Real Director General Jorge Valdano said on Sunday.
"If there was just one team that had the habit of being heroic, it would be Real Madrid. Nothing should deprive us of feeling hope and excitement for Tuesday's match."
English Premier League leaders Manchester United will defend a 2-0 advantage over Schalke 04 when they host the Bundesliga side in Wednesday's other semi. The final is at London's Wembley stadium on May 28.
Probable teams:
Barcelona: 1-Victor Valdes; 2-Daniel Alves, 3-Gerard Pique, 14-Javier Mascherano, 5-Carles Puyol; 16-Sergio Busquets, 6-Xavi, 15-Seydou Keita; 17-Pedro, 10-Lionel Messi, 7-David Villa.
Real Madrid: 1-Iker Casillas; 17-Alvaro Arbeloa, 2-Ricardo Carvalho, 18-Raul Albiol, 12-Marcelo; 10-Lassana Diarra, 14-Xabi Alonso, 24-Sami Khedira; 23-Mesut Ozil, 7-Cristiano Ronaldo, 22-Angel Di Maria.
Referee: Frank De Bleeckere (Belgium).
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