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Metallic hydrogen, once theory, becomes a reality!

January 29, 2017 19:38 IST

Nearly a century after it was theorised, Harvard scientists claim to have succeeded in creating the rarest and potentially one of the most valuable materials on the planet -- atomic metallic hydrogen.

In addition to helping scientists answer fundamental questions about the nature of matter, the material is theorised to have a wide range of applications, including as a room-temperature superconductor.

"This is the holy grail of high-pressure physics," said Professor Isaac Silvera from Harvard University in the US.

"It's the first-ever sample of metallic hydrogen on Earth, so when you're looking at it, you're looking at something that's never existed before," said Silvera.

To create it, researchers squeezed a tiny hydrogen sample at 495 gigapascal, or more than 71.7 million pounds-per-square inch -- greater than the pressure at the centre of the Earth.

At those extreme pressures, solid molecular hydrogen breaks down and the tightly bound molecules dissociate to transform into atomic hydrogen, which is a metal, Silvera said.

While the research offers an important new window into understanding the general properties of hydrogen, it also offers tantalising hints at potentially revolutionary new materials.

"One prediction that's very important is metallic hydrogen is predicted to be meta-stable," Silvera said.

"That means if you take the pressure off, it will stay metallic, similar to the way diamonds form from graphite under intense heat and pressure, but remains a diamond when that pressure and heat is removed," he said.

Understanding whether the material is stable is important, Silvera said, because predictions suggest metallic hydrogen could act as a superconductor at room temperatures.

"That would be revolutionary. As much as 15 per cent of energy is lost to dissipation during transmission, so if you could make wires from this material and use them in the electrical grid, it could change that story," he said.

A room temperature superconductor could radically change our transportation system, making magnetic levitation of high-speed trains possible, as well as making electric cars more efficient and improving the performance of many electronic devices, said Ranga Dias, post-doctoral fellow at Harvard.

The material could also provide major improvements in energy production and storage - because superconductors have zero resistance energy could be stored by maintaining currents in superconducting coils, and then be used when needed.

Though it has the potential to transform life on Earth, metallic hydrogen could also play a key role in helping humans explore the far reaches of space, as the most powerful rocket propellant yet discovered, researchers said.

"It takes a tremendous amount of energy to make metallic hydrogen," Silvera said.

"And if you convert it back to molecular hydrogen, all that energy is released, so it would make it the most powerful rocket propellant known to man, and could revolutionise rocketry," he said.

The most powerful fuels in use today are characterised by a "specific impulse" -- a measure, in seconds, of how fast a propellant is fired from the back of a rocket -- of 450 seconds. The specific impulse for metallic hydrogen, by comparison, is theorised to be 1,700 seconds.

"That would easily allow you to explore the outer planets. We would be able to put rockets into orbit with only one stage, versus two, and could send up larger payloads, so it could be very important," Silvera said.

To create the new material, Silvera and Dias turned to one of the hardest materials on Earth -- diamond.

Rather than natural diamond, Silvera and Dias used two small pieces of carefully polished synthetic diamond which were then treated to make them even tougher and then mounted opposite each other in a device known as a diamond anvil cell.

"Diamonds are polished with diamond powder, and that can gouge out carbon from the surface. When we looked at the diamond using atomic force microscopy, we found defects, which could cause it to weaken and break," Silvera said.

The solution, he said, was to use a reactive ion etching process to shave a tiny layer -- just five microns thick, or about one-tenth of a human hair -- from the diamond's surface.

The diamonds were then coated with a thin layer of alumina to prevent the hydrogen from diffusing into their crystal structure and embrittling them.

The research was published in the journal Science.

Image: As scientists pressed hydrogen between two diamonds, it changed from transparent (left) to black (middle) and, finally, to a reflective state (right). That reflectivity indicates that the hydrogen transformed into a metal, researchers claim.

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